Yttrium acetylacetonate
| |
| Identifiers | |
|---|---|
| ECHA InfoCard | 100.035.991 |
| Properties | |
| C15H27O9Y | |
| Molar mass | 440.278 g·mol−1 |
| Melting point | 131 °C (404 K)[1] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Yttrium acetylacetonate is a coordination compound with the chemical formula Y(C5H7O2)3(H2O)x, or Y(acac)3(H2O)x for short. The value of x can vary from 1 to 3.[2]
Upon heating under vacuum, the hydrates convert to the oxo-cluster Y4O(C5H7O2)10. This behavior is also observed for gadolinium acetylacetonate, europium acetylacetonate, lanthanum acetylacetonate, and erbium acetylacetonate.[3]
References
- ^ Jantsch, G.; Meyer, E. Addition compounds in the acetylacetonates of the rare earths. Berichte der Deutschen Chemischen Gesellschaft [Abteilung] B: Abhandlungen, 1920. 53B: 1577-1587. ISSN 0365-9488.
- ^ Cunningham, James A.; Sands, Donald E.; Wagner, William Frederick (1967). "Crystal and Molecular Structure of Yttrium Acetylacetonate Trihydrate". Inorganic Chemistry. 6 (3): 499–503. doi:10.1021/ic50049a014.
- ^ Tamang, Sem Raj; Singh, Arpita; Bedi, Deepika; Bazkiaei, Adineh Rezaei; Warner, Audrey A.; Glogau, Keeley; McDonald, Corey; Unruh, Daniel K.; Findlater, Michael (2020). "Polynuclear Lanthanide–Diketonato Clusters for the Catalytic Hydroboration of Carboxamides and Esters". Nat. Catal. 3 (2): 154–162. doi:10.1038/s41929-019-0405-5. S2CID 209897045.