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{{About||the music group|Water on Mars (band)|the Doctor Who episode|The Waters of Mars}}
{{About||the music group|Water on Mars (band)|the Doctor Who episode|The Waters of Mars}}
{{Use mdy dates|date=August 2011}}
{{Use mdy dates|date=August 2011}}
[[File:AncientMars.jpg|thumb|An artist's impression of what ancient Mars may have looked like, based on [[Mars Ocean Hypothesis#Observational evidence|geological data]]]]
[[File:AncientMars.jpg|thumb|An artist's impression of what ancient Mars may have looked like, based on [[Mars Ocean Hypothesis#Observational evidence|geological data]]]]
[[Water]] on [[Mars]] exists today almost exclusively as ice, with a small amount present in the [[Atmosphere of Mars|atmosphere]] as vapour.<ref>Jakosky, B.M.; Haberle, R.M. (1992). The Seasonal Behavior of Water on Mars in ''Mars,'' H.H. Kieffer et al., Eds; University of Arizona Press: Tucson, AZ, pp 969–1016.</ref> The only place where water ice is visible at the surface is at the [[Martian polar ice caps|north polar ice cap]].<ref>Carr, M.H. (1996). ''Water on Mars;'' Oxford University Press: New York, p 197.</ref> However, abundant water ice is also present beneath the permanent [[dry ice|carbon dioxide]] ice cap at the Martian south pole and in the shallow subsurface at more temperate latitudes.<ref>Bibring, J.-P. et al. (2004). Perennial Water Ice Identified in the South Polar Cap of Mars. ''Nature,'' '''428''' 627–630.</ref><ref name=ESAwater>{{cite news| title=Water at Martian south pole| date=17 March 2004| publisher=European Space Agency (ESA)|url=http://www.esa.int/SPECIALS/Mars_Express/SEMYKEX5WRD_0.html |work=| pages=| accessdate=2009-09-11}}</ref><ref name="mars.jpl.nasa.gov">{{cite web| url=http://mars.jpl.nasa.gov/odyssey/newsroom/pressreleases/20020528a.html |title=Mars Odyssey: Newsroom |publisher=Mars.jpl.nasa.gov |date=May 28, 2002 |accessdate=December 19, 2010}}</ref><ref name="Feildman, T. 2004">{{cite journal | year=2004 | last1=Feldman | first1=W.C. et al. |title= Global Distribution of Near-Surface Hydrogen on Mars | journal=J. Geophysical Research |volume= 109 |doi = 10.1029/2003JE002160 | bibcode=2004JGRE..10909006F}}</ref> More than five million cubic kilometers of ice have been identified at or near the surface of modern Mars, enough to cover the whole planet to a depth of 35 meters.<ref name="ChristensenIceBudget" /> Even more ice is likely to be locked away in the deep subsurface.<ref>Carr, 2006, p. 173.</ref>
[[Water]] on [[Mars]] exists today almost exclusively as ice, with a small amount present in the [[Atmosphere of Mars|atmosphere]] as vapour.<ref>Jakosky, B.M.; Haberle, R.M. (1992). The Seasonal Behavior of Water on Mars in ''Mars,'' H.H. Kieffer et al., Eds; University of Arizona Press: Tucson, AZ, pp 969–1016.</ref> The only place where water ice is visible at the surface is at the [[Martian polar ice caps|north polar ice cap]].<ref>Carr, M.H. (1996). ''Water on Mars;'' Oxford University Press: New York, p 197.</ref> However, abundant water ice is also present beneath the permanent [[dry ice|carbon dioxide]] ice cap at the Martian south pole and in the shallow subsurface at more temperate latitudes.<ref>Bibring, J.-P. et al. (2004). Perennial Water Ice Identified in the South Polar Cap of Mars. ''Nature,'' '''428''' 627–630.</ref><ref name=ESAwater>{{cite news| title=Water at Martian south pole| date=17 March 2004| publisher=European Space Agency (ESA)|url=http://www.esa.int/SPECIALS/Mars_Express/SEMYKEX5WRD_0.html |work=| pages=| accessdate=2009-09-11}}</ref><ref name="mars.jpl.nasa.gov">{{cite web| url=http://mars.jpl.nasa.gov/odyssey/newsroom/pressreleases/20020528a.html |title=Mars Odyssey: Newsroom |publisher=Mars.jpl.nasa.gov |date=May 28, 2002 |accessdate=December 19, 2010}}</ref><ref name="Feildman, T. 2004">{{cite journal | year=2004 | last1=Feldman | first1=W.C. et al. |title= Global Distribution of Near-Surface Hydrogen on Mars | journal=J. Geophysical Research |volume= 109 |doi = 10.1029/2003JE002160 | bibcode=2004JGRE..10909006F}}</ref> More than five million cubic kilometers of ice have been identified at or near the surface of modern Mars, enough to cover the whole planet to a depth of 35 meters.<ref name="ChristensenIceBudget" /> Even more ice is likely to be locked away in the deep subsurface.<ref>Carr, 2006, p. 173.</ref>


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Many lines of evidence indicate that water is abundant on Mars and has played a significant role in the planet's [[Geology of Mars|geologic history]].<ref name="lpi.usra.edu">{{cite journal | last1=Parker |first1= T. |year= 2000 | title=Argyre Planitia and the Mars Global Hydrologic Cycle| volume=XXXI | bibcode = 2000LPI....31.2033P | journal=Lunar and Planetary Science | url=http://www.lpi.usra.edu/meetings/lpsc2000/pdf/2033.pdf | format=PDF | last2=Clifford | first2=S. M. | last3=Banerdt | first3=W. B. | page=2033}}</ref><ref name="Heisinger2002">{{cite journal | doi = 10.1016/S0032-0633(02)00054-5 | last1 = Heisinger | first1 = H. | last2 = Head | first2 = J. | author-separator =, | author-name-separator= | year = 2002 | title = Topography and morphology of the Argyre basin, Mars: implications for its geologic and hydrologic history | url = | journal=Planet. Space Sci. | volume = 50 | pages = 939–981 | bibcode=2002P&SS...50..939H | issue = 10–11}}</ref> The present-day inventory of water on Mars can be estimated from spacecraft imagery, [[remote sensing]] techniques ([[Spectroscopy|spectroscopic]] measurements,<ref>Soderblom, L.A. (1992). The Composition and Mineralogy of the Martian Surface from Spectroscopic Observations: 0.3μm to 50 μm. In Mars, H.H. Kieffer et al., Eds.; University of Arizona Press: Tucson, AZ, pp. 557–593, ISBN 0-8165-1257-4.</ref><ref>Glotch, T. and P. Christensen. 2005. Geologic and mineralogical mapping of Aram Chaos: Evidence for water-rich history. J. Geophys. Res. 110. {{DOI|10.1029/2004JE002389}}</ref> [[radar]],<ref name="Holt, J. 2008">{{cite journal | bibcode = 2008LPI....39.2441H |year=2008 | title= Radar Sounding Evidence for Ice within Lobate Debris Aprons near Hellas Basin, Mid-Southern Latitudes of Mars |journal=Lunar and Planetary Science |volume= XXXIX |url=http://www.lpi.usra.edu/meetings/lpsc2008/pdf/2441.pdf | author1 = Holt | first1 = J. W. | last2 = Safaeinili | first2 = A. | last3 = Plaut | first3 = J. J. | last4 = Young | first4 = D. A. | last5 = Head | first5 = J. W. | last6 = Phillips | first6 = R. J. | last7 = Campbell | first7 = B. A. | last8 = Carter | first8 = L. M. | last9 = Gim | first9 = Y. | page = 2441 }}</ref> etc.,), and surface investigations from landers and rovers.<ref name='Amos June 2013'>{{cite news | first = Jonathan Amos | title = Old Opportunity Mars rover makes rock discovery | date = 10 June 2013 | publisher = BBC News | url = http://www.bbc.co.uk/news/science-environment-22832673 | work = NASA | accessdate = 2013-06-14}}</ref><ref name='Clay clues'>{{cite news | title = Mars Rover Opportunity Examines Clay Clues in Rock | date = May 17, 2013 | publisher = Jet Propulsion Laboratory | url = http://www.jpl.nasa.gov/news/news.php?release=2013-167 | work = NASA | accessdate = 2013-06-14}}</ref> Geologic evidence of past water includes enormous [[outflow channels]] carved by floods; ancient river [[Valley networks (Mars)|valley networks]],<ref name="Harrison 2005">{{cite journal | last1 = Harrison | first1 = K | last2 = Grimm | first2 = R. | author-separator =; | author-name-separator= | year = 2005 | title = Groundwater-controlled valley networks and the decline of surface runoff on early Mars | url = | journal=Journal of Geophysical Research | volume = 110 | doi = 10.1029/2005JE002455 | bibcode=2005JGRE..11012S16H}}</ref><ref name="Howard, A. 2005">{{cite journal | last1 = Howard | first1 = A. | last2 = Moore | year = 2005 | first2 = Jeffrey M. | last3 = Irwin | first3 = Rossman P. | title = An intense terminal epoch of widespread fluvial activity on early Mars: 1. Valley network incision and associated deposits | url = | journal=Journal of Geophysical Research | volume = 110 |doi = 10.1029/2005JE002459 | bibcode=2005JGRE..11012S14H}}</ref> [[River delta|deltas]], and [[dry lake|lakebeds]];<ref name="Irwin III 2005" /><ref name="Fassett2008">{{cite journal | doi = 10.1016/j.icarus.2008.06.016 | last1 = Fassett | first1 = C. | last2 = Head | first2 = III | author-separator =, | author-name-separator= | year = 2008 | title = Valley network-fed, open-basin lakes on Mars: Distribution and implications for Noachian surface and subsurface hydrology | url = | journal=Icarus | volume = 198 | pages = 37–56 | bibcode=2008Icar..198...37F}}</ref><ref name="Moore2001">{{cite journal | doi = 10.1006/icar.2001.6736 | last1 = Moore | first1 = J. | last2 = Wilhelms | first2 = D. | author-separator =, | author-name-separator= | year = 2001 | title = Hellas as a possible site of ancient ice-covered lakes on Mars | url =http://ntrs.nasa.gov/archive/nasa/casi.ntrs.nasa.gov/20020050249_2002081883.pdf | journal=Icarus | volume = 154 | pages = 258–276 | bibcode=2001Icar..154..258M | issue = 2}}</ref><ref name="http">{{cite journal | last1=Weitz |first1= C. |first2= T. |last2=Parker |year= 2000 |title= New evidence that the Valles Marineris interior deposits formed in standing bodies of water | journal=Lunar and Planetary Science |volume= XXXI | bibcode = 2000LPI....31.1693W | url =http://www.lpi.usra.edu/meetings/lpsc2000/pdf/1693.pdf | format=PDF | page=1693}}</ref> and the detection of rocks and minerals on the surface that could only have formed in liquid water.<ref>{{cite web|url=http://www.space.com/6033-signs-ancient-mars-wet.html |title=New Signs That Ancient Mars Was Wet |publisher=Space.com |date=2008-10-28 |accessdate=2013-02-10}}</ref> Numerous [[Geomorphology|geomorphic]] features suggest the presence of ground ice ([[permafrost]])<ref>Squyres, S.W. et al. (1992). Ice in the Martian Regolith. In Mars, H.H. Kieffer et al., Eds.; University of Arizona Press: Tucson, AZ, pp. 523–554, ISBN 0-8165-1257-4.</ref> and the movement of ice in [[glacier]]s, both in the recent past<ref name='Tropical snow'>{{cite journal | last1= Head | first1= JW | last2= Neukum | first2= G | last3= Jaumann | first3= R | last4= Hiesinger | first4= H | last5= Hauber | first5= E | last6= Carr | first6= M | last7= Masson | first7= P | last8= Foing | first8= B | last9= Hoffmann | first9= H | title= Tropical to mid-latitude snow and ice accumulation, flow and glaciation on Mars | journal= Nature | volume= 434 | issue= 7031 |pages= 346–350 | year= 2005 | pmid = 15772652 | doi= 10.1038/nature03359 |bibcode = 2005Natur.434..346H }}</ref><ref name="HeadMarchant2006">Head, J. and D. Marchant. 2006. Modifications of the walls of a Noachian crater in Northern Arabia Terra (24 E, 39 N) during northern mid-latitude Amazonian glacial epochs on Mars: Nature and evolution of Lobate Debris Aprons and their relationships to lineated valley fill and glacial systems. Lunar. Planet. Sci. 37. Abstract 1128</ref><ref>Head, J., et al. 2006. Modification if the dichotomy boundary on Mars by Amazonian mid-latitude regional glaciation. Geophys. Res Lett. 33</ref><ref>Head, J. and D. Marchant. 2006. Evidence for global-scale northern mid-latitude glaciation in the Amazonian period of Mars: Debris-covered glacial and valley glacial deposits in the 30 – 50 N latitude band. Lunar. Planet. Sci. 37. Abstract 1127</ref><ref name='in flux'>{{cite web|author=Source: Brown University Posted Monday, October 17, 2005 |url=http://www.spaceref.com/news/viewpr.html?pid=18050 |title=Mars' climate in flux: Mid-latitude glaciers |publisher=Marstoday |date=2005-10-17 |accessdate=2013-06-13}}</ref><ref name='Richard Lewis'>{{cite web| author=Richard Lewis |url=http://news.brown.edu/pressreleases/2008/04/martian-glaciers |title=Glaciers Reveal Martian Climate Has Been Recently Active |publisher=Brown University |date=2008-04-23 |accessdate=2013-02-10}}</ref> and present.<ref name="Plaut, J. 2008">{{cite journal | last1=Plaut | first1=Jeffrey J. | last2=Safaeinili | first2=Ali | last3=Holt | first3=John W. | last4=Phillips | first4=Roger J. | last5=Head | first5=James W. | last6=Seu | first6=Roberto | last7=Putzig | first7=Nathaniel E. | last8=Frigeri | first8=Alessandro | title=Radar Evidence for Ice in Lobate Debris Aprons in the Mid-Northern Latitudes of Mars | doi = 10.1029/2008GL036379 | year=2009 | volume=36 | journal=Geophysical Research Letters | url=http://www.planetary.brown.edu/pdfs/3733.pdf | bibcode=2009GeoRL..3602203P | issue=2}}</ref> [[Gully (Mars)|Gullies]] and [[Seasonal flows on warm Martian slopes|slope lineae]] along cliffs and crater walls suggest that flowing water continues to shape the surface of Mars, although to a far lesser degree than in the ancient past.
Many lines of evidence indicate that water is abundant on Mars and has played a significant role in the planet's [[Geology of Mars|geologic history]].<ref name="lpi.usra.edu">{{cite journal | last1=Parker |first1= T. |year= 2000 | title=Argyre Planitia and the Mars Global Hydrologic Cycle| volume=XXXI | bibcode = 2000LPI....31.2033P | journal=Lunar and Planetary Science | url=http://www.lpi.usra.edu/meetings/lpsc2000/pdf/2033.pdf | format=PDF | last2=Clifford | first2=S. M. | last3=Banerdt | first3=W. B. | page=2033}}</ref><ref name="Heisinger2002">{{cite journal | doi = 10.1016/S0032-0633(02)00054-5 | last1 = Heisinger | first1 = H. | last2 = Head | first2 = J. | author-separator =, | author-name-separator= | year = 2002 | title = Topography and morphology of the Argyre basin, Mars: implications for its geologic and hydrologic history | url = | journal=Planet. Space Sci. | volume = 50 | pages = 939–981 | bibcode=2002P&SS...50..939H | issue = 10–11}}</ref> The present-day inventory of water on Mars can be estimated from spacecraft imagery, [[remote sensing]] techniques ([[Spectroscopy|spectroscopic]] measurements,<ref>Soderblom, L.A. (1992). The Composition and Mineralogy of the Martian Surface from Spectroscopic Observations: 0.3μm to 50 μm. In Mars, H.H. Kieffer et al., Eds.; University of Arizona Press: Tucson, AZ, pp. 557–593, ISBN 0-8165-1257-4.</ref><ref>Glotch, T. and P. Christensen. 2005. Geologic and mineralogical mapping of Aram Chaos: Evidence for water-rich history. J. Geophys. Res. 110. {{DOI|10.1029/2004JE002389}}</ref> [[radar]],<ref name="Holt, J. 2008">{{cite journal | bibcode = 2008LPI....39.2441H |year=2008 | title= Radar Sounding Evidence for Ice within Lobate Debris Aprons near Hellas Basin, Mid-Southern Latitudes of Mars |journal=Lunar and Planetary Science |volume= XXXIX |url=http://www.lpi.usra.edu/meetings/lpsc2008/pdf/2441.pdf | author1 = Holt | first1 = J. W. | last2 = Safaeinili | first2 = A. | last3 = Plaut | first3 = J. J. | last4 = Young | first4 = D. A. | last5 = Head | first5 = J. W. | last6 = Phillips | first6 = R. J. | last7 = Campbell | first7 = B. A. | last8 = Carter | first8 = L. M. | last9 = Gim | first9 = Y. | page = 2441 }}</ref> etc.,), and surface investigations from landers and rovers.<ref name='Amos June 2013'>{{cite news | first = Jonathan Amos | title = Old Opportunity Mars rover makes rock discovery | date = 10 June 2013 | publisher = BBC News | url = http://www.bbc.co.uk/news/science-environment-22832673 | work = NASA | accessdate = 2013-06-14}}</ref><ref name='Clay clues'>{{cite news | title = Mars Rover Opportunity Examines Clay Clues in Rock | date = May 17, 2013 | publisher = Jet Propulsion Laboratory | url = http://www.jpl.nasa.gov/news/news.php?release=2013-167 | work = NASA | accessdate = 2013-06-14}}</ref> Geologic evidence of past water includes enormous [[outflow channels]] carved by floods; ancient river [[Valley networks (Mars)|valley networks]],<ref name="Harrison 2005">{{cite journal | last1 = Harrison | first1 = K | last2 = Grimm | first2 = R. | author-separator =; | author-name-separator= | year = 2005 | title = Groundwater-controlled valley networks and the decline of surface runoff on early Mars | url = | journal=Journal of Geophysical Research | volume = 110 | doi = 10.1029/2005JE002455 | bibcode=2005JGRE..11012S16H}}</ref><ref name="Howard, A. 2005">{{cite journal | last1 = Howard | first1 = A. | last2 = Moore | year = 2005 | first2 = Jeffrey M. | last3 = Irwin | first3 = Rossman P. | title = An intense terminal epoch of widespread fluvial activity on early Mars: 1. Valley network incision and associated deposits | url = | journal=Journal of Geophysical Research | volume = 110 |doi = 10.1029/2005JE002459 | bibcode=2005JGRE..11012S14H}}</ref> [[River delta|deltas]], and [[dry lake|lakebeds]];<ref name="Irwin III 2005" /><ref name="Fassett2008">{{cite journal | doi = 10.1016/j.icarus.2008.06.016 | last1 = Fassett | first1 = C. | last2 = Head | first2 = III | author-separator =, | author-name-separator= | year = 2008 | title = Valley network-fed, open-basin lakes on Mars: Distribution and implications for Noachian surface and subsurface hydrology | url = | journal=Icarus | volume = 198 | pages = 37–56 | bibcode=2008Icar..198...37F}}</ref><ref name="Moore2001">{{cite journal | doi = 10.1006/icar.2001.6736 | last1 = Moore | first1 = J. | last2 = Wilhelms | first2 = D. | author-separator =, | author-name-separator= | year = 2001 | title = Hellas as a possible site of ancient ice-covered lakes on Mars | url =http://ntrs.nasa.gov/archive/nasa/casi.ntrs.nasa.gov/20020050249_2002081883.pdf | journal=Icarus | volume = 154 | pages = 258–276 | bibcode=2001Icar..154..258M | issue = 2}}</ref><ref name="http">{{cite journal | last1=Weitz |first1= C. |first2= T. |last2=Parker |year= 2000 |title= New evidence that the Valles Marineris interior deposits formed in standing bodies of water | journal=Lunar and Planetary Science |volume= XXXI | bibcode = 2000LPI....31.1693W | url =http://www.lpi.usra.edu/meetings/lpsc2000/pdf/1693.pdf | format=PDF | page=1693}}</ref> and the detection of rocks and minerals on the surface that could only have formed in liquid water.<ref>{{cite web|url=http://www.space.com/6033-signs-ancient-mars-wet.html |title=New Signs That Ancient Mars Was Wet |publisher=Space.com |date=2008-10-28 |accessdate=2013-02-10}}</ref> Numerous [[Geomorphology|geomorphic]] features suggest the presence of ground ice ([[permafrost]])<ref>Squyres, S.W. et al. (1992). Ice in the Martian Regolith. In Mars, H.H. Kieffer et al., Eds.; University of Arizona Press: Tucson, AZ, pp. 523–554, ISBN 0-8165-1257-4.</ref> and the movement of ice in [[glacier]]s, both in the recent past<ref name='Tropical snow'>{{cite journal | last1= Head | first1= JW | last2= Neukum | first2= G | last3= Jaumann | first3= R | last4= Hiesinger | first4= H | last5= Hauber | first5= E | last6= Carr | first6= M | last7= Masson | first7= P | last8= Foing | first8= B | last9= Hoffmann | first9= H | title= Tropical to mid-latitude snow and ice accumulation, flow and glaciation on Mars | journal= Nature | volume= 434 | issue= 7031 |pages= 346–350 | year= 2005 | pmid = 15772652 | doi= 10.1038/nature03359 |bibcode = 2005Natur.434..346H }}</ref><ref name="HeadMarchant2006">Head, J. and D. Marchant. 2006. Modifications of the walls of a Noachian crater in Northern Arabia Terra (24 E, 39 N) during northern mid-latitude Amazonian glacial epochs on Mars: Nature and evolution of Lobate Debris Aprons and their relationships to lineated valley fill and glacial systems. Lunar. Planet. Sci. 37. Abstract 1128</ref><ref>Head, J., et al. 2006. Modification if the dichotomy boundary on Mars by Amazonian mid-latitude regional glaciation. Geophys. Res Lett. 33</ref><ref>Head, J. and D. Marchant. 2006. Evidence for global-scale northern mid-latitude glaciation in the Amazonian period of Mars: Debris-covered glacial and valley glacial deposits in the 30 – 50 N latitude band. Lunar. Planet. Sci. 37. Abstract 1127</ref><ref name='in flux'>{{cite web|author=Source: Brown University Posted Monday, October 17, 2005 |url=http://www.spaceref.com/news/viewpr.html?pid=18050 |title=Mars' climate in flux: Mid-latitude glaciers |publisher=Marstoday |date=2005-10-17 |accessdate=2013-06-13}}</ref><ref name='Richard Lewis'>{{cite web| author=Richard Lewis |url=http://news.brown.edu/pressreleases/2008/04/martian-glaciers |title=Glaciers Reveal Martian Climate Has Been Recently Active |publisher=Brown University |date=2008-04-23 |accessdate=2013-02-10}}</ref> and present.<ref name="Plaut, J. 2008">{{cite journal | last1=Plaut | first1=Jeffrey J. | last2=Safaeinili | first2=Ali | last3=Holt | first3=John W. | last4=Phillips | first4=Roger J. | last5=Head | first5=James W. | last6=Seu | first6=Roberto | last7=Putzig | first7=Nathaniel E. | last8=Frigeri | first8=Alessandro | title=Radar Evidence for Ice in Lobate Debris Aprons in the Mid-Northern Latitudes of Mars | doi = 10.1029/2008GL036379 | year=2009 | volume=36 | journal=Geophysical Research Letters | url=http://www.planetary.brown.edu/pdfs/3733.pdf | bibcode=2009GeoRL..3602203P | issue=2}}</ref> [[Gully (Mars)|Gullies]] and [[Seasonal flows on warm Martian slopes|slope lineae]] along cliffs and crater walls suggest that flowing water continues to shape the surface of Mars, although to a far lesser degree than in the ancient past.


Although the surface of Mars was periodically wet and could have been hospitable to microbial life billions of years ago,<ref name='Wall'>{{cite news |last=Wall |first=Mike |title=Q & A with Mars Life-Seeker Chris Carr |date=25 March 2011 |url=http://www.space.com/11232-mars-life-evolution-carr-interview.html |work=Space.com | accessdate=2011-03-25}}</ref> the current environment at the surface is dry and subfreezing, probably presenting an insurmountable obstacle for living organisms. In addition, Mars lacks a thick atmosphere, [[ozone layer]], and [[Earth's magnetic field|magnetic field]], allowing solar and [[cosmic radiation]] to strike the surface unimpeded. The damaging effects of ionizing radiation on cellular structure is another one of the prime limiting factors on the survival of life on the surface.<ref name='Dartnell-1'>{{cite journal | title = Modelling the surface and subsurface Martian radiation environment: Implications for astrobiology | journal = Geophysical Research Letters | date = 30 January 2007 | first = L.R. | last = Dartnell | coauthors = Desorgher, Ward, Coates | volume = 34 | issue = 2 | doi = 10.1029/2006GL027494 | url = http://onlinelibrary.wiley.com/doi/10.1029/2006GL027494/abstract | accessdate = 2013-05-26 | quote = The damaging effect of ionising radiation on cellular structure is one of the prime limiting factors on the survival of life in potential astrobiological habitats.|bibcode = 2007GeoRL..34.2207D }}</ref><ref name='ionising radiation'>{{cite journal | title = Martian sub-surface ionising radiation: biosignatures and geology | journal = Biogeosciences | year = 2007 | first = L. R. Dartnell | coauthors = L. Desorgher, J. M. Ward, A. J. Coates4 | volume = 4 | pages = 545–558 | url = http://www.biogeosciences.net/4/545/2007/bg-4-545-2007.html | accessdate = 2013-06-01 | quote = This ionising radiation field is deleterious to the survival of dormant cells or spores and the persistence of molecular biomarkers in the subsurface, and so its characterisation. [..] Even at a depth of 2 meters beneath the surface, any microbes would likely be dormant, cryopreserved by the current freezing conditions, and so metabolically inactive and unable to repair cellular degradation as it occurs.|bibcode = 2007BGeo....4..545D | doi=10.5194/bg-4-545-2007}}</ref> Therefore, the best potential locations for discovering [[life on Mars]] may be in subsurface environments.<ref name='subsurface habitability model'>{{cite journal | title = A Possible Biochemical Model for Mars | journal = 43rd Lunar and Planetary Science Conference (2012) | year = 2012 | first = A. de Morais | url = http://www.lpi.usra.edu/meetings/lpsc2012/pdf/2943.pdf | format = PDF | accessdate = 2013-06-05 | quote = The extensive volcanism at that time much possibly created subsurface cracks and caves within different strata, and the liquid water could have been stored in these subterraneous places, forming large aquifers with deposits of saline liquid water, minerals organic molecules, and geothermal heat – ingredients for life as we know on Earth.}}</ref><ref name='Parnell' /><ref name=Steigerwald>{{cite news| first=Bill| last=Steigerwald| title=Martian Methane Reveals the Red Planet is not a Dead Planet| date=January 15, 2009 |publisher=NASA |url=http://www.nasa.gov/mission_pages/mars/news/marsmethane.html |work=NASA's Goddard Space Flight Center| pages=| accessdate=June 6 24, 2013| quote= If microscopic Martian life is producing the methane, it likely resides far below the surface, where it's still warm enough for liquid water to exist}}</ref>
Although the surface of Mars was periodically wet and could have been hospitable to microbial life billions of years ago,<ref name='Wall'>{{cite news |last=Wall |first=Mike |title=Q & A with Mars Life-Seeker Chris Carr |date=25 March 2011 |url=http://www.space.com/11232-mars-life-evolution-carr-interview.html |work=Space.com | accessdate=2011-03-25}}</ref> the current environment at the surface is dry and subfreezing, probably presenting an insurmountable obstacle for living organisms. In addition, Mars lacks a thick atmosphere, [[ozone layer]], and [[Earth's magnetic field|magnetic field]], allowing solar and [[cosmic radiation]] to strike the surface unimpeded. The damaging effects of ionizing radiation on cellular structure is another one of the prime limiting factors on the survival of life on the surface.<ref name='Dartnell-1'>{{cite journal | title = Modelling the surface and subsurface Martian radiation environment: Implications for astrobiology | journal = Geophysical Research Letters | date = 30 January 2007 | first = L.R. | last = Dartnell |author2=Desorgher|author3=Ward|author4=Coates| volume = 34 | issue = 2 | doi = 10.1029/2006GL027494 | url = http://onlinelibrary.wiley.com/doi/10.1029/2006GL027494/abstract | accessdate = 2013-05-26 | quote = The damaging effect of ionising radiation on cellular structure is one of the prime limiting factors on the survival of life in potential astrobiological habitats.|bibcode = 2007GeoRL..34.2207D }}</ref><ref name='ionising radiation'>{{cite journal | title = Martian sub-surface ionising radiation: biosignatures and geology | journal = Biogeosciences | year = 2007 | first = L. R. Dartnell |first2=L.|last2=Desorgher|first3=J. M.|last3=Ward|first4=A. J.|last4=Coates4| volume = 4 | pages = 545–558 | url = http://www.biogeosciences.net/4/545/2007/bg-4-545-2007.html | accessdate = 2013-06-01 | quote = This ionising radiation field is deleterious to the survival of dormant cells or spores and the persistence of molecular biomarkers in the subsurface, and so its characterisation. [..] Even at a depth of 2 meters beneath the surface, any microbes would likely be dormant, cryopreserved by the current freezing conditions, and so metabolically inactive and unable to repair cellular degradation as it occurs.|bibcode = 2007BGeo....4..545D | doi=10.5194/bg-4-545-2007}}</ref> Therefore, the best potential locations for discovering [[life on Mars]] may be in subsurface environments.<ref name='subsurface habitability model'>{{cite journal | title = A Possible Biochemical Model for Mars | journal = 43rd Lunar and Planetary Science Conference (2012) | year = 2012 | first = A. de Morais | url = http://www.lpi.usra.edu/meetings/lpsc2012/pdf/2943.pdf | format = PDF | accessdate = 2013-06-05 | quote = The extensive volcanism at that time much possibly created subsurface cracks and caves within different strata, and the liquid water could have been stored in these subterraneous places, forming large aquifers with deposits of saline liquid water, minerals organic molecules, and geothermal heat – ingredients for life as we know on Earth.}}</ref><ref name='Parnell' /><ref name=Steigerwald>{{cite news| first=Bill| last=Steigerwald| title=Martian Methane Reveals the Red Planet is not a Dead Planet| date=January 15, 2009 |publisher=NASA |url=http://www.nasa.gov/mission_pages/mars/news/marsmethane.html |work=NASA's Goddard Space Flight Center| pages=| accessdate=June 6 24, 2013| quote= If microscopic Martian life is producing the methane, it likely resides far below the surface, where it's still warm enough for liquid water to exist}}</ref>
[[File:Channels near Warrego in Thaumasia.JPG|thumb|Dry channels near [[Warrego Valles]] ]]
[[File:Channels near Warrego in Thaumasia.JPG|thumb|Dry channels near [[Warrego Valles]] ]]


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The final piece of the Martian climate puzzle was provided by [[Mariner 4]] in 1965. Grainy television pictures from the spacecraft showed a surface dominated by [[impact crater]]s, which implied that the surface was very old and had not experienced the level of erosion and tectonic activity seen on Earth. Little erosion meant that liquid water had probably not played a large role in the planet's [[geomorphology]] for billions of years.<ref>Leighton, R.B.; Murray, B.C.; Sharp, R.P.; Allen, J.D.; Sloan, R.K. (1965). Mariner IV Photography of Mars: Initial Results. ''Science,'' '''149'''(3684), 627–630.</ref> Furthermore, the variations in the radio signal from the spacecraft as it passed behind the planet allowed scientists to calculate the density of the atmosphere. The results showed an atmospheric pressure less than 1% of Earth’s at sea level, effectively precluding the existence of liquid water, which would rapidly boil or freeze at such low pressures.<ref>Kliore, A. et al. (1965). Occultation Experiment: Results of the First Direct Measurement of Mars's Atmosphere and Ionosphere. ''Science,'' '''149'''(3689), 1243–1248, {{DOI|10.1126/science.149.3689.1243}} PMID 17747455</ref> Thus, a vision of Mars was born of a world much like the Moon but with just a wisp of an atmosphere to blow the dust around. This view of Mars would last nearly another decade until [[Mariner 9]] showed a much more dynamic Mars with hints that the planet’s past environment was more clement than the present one.
The final piece of the Martian climate puzzle was provided by [[Mariner 4]] in 1965. Grainy television pictures from the spacecraft showed a surface dominated by [[impact crater]]s, which implied that the surface was very old and had not experienced the level of erosion and tectonic activity seen on Earth. Little erosion meant that liquid water had probably not played a large role in the planet's [[geomorphology]] for billions of years.<ref>Leighton, R.B.; Murray, B.C.; Sharp, R.P.; Allen, J.D.; Sloan, R.K. (1965). Mariner IV Photography of Mars: Initial Results. ''Science,'' '''149'''(3684), 627–630.</ref> Furthermore, the variations in the radio signal from the spacecraft as it passed behind the planet allowed scientists to calculate the density of the atmosphere. The results showed an atmospheric pressure less than 1% of Earth’s at sea level, effectively precluding the existence of liquid water, which would rapidly boil or freeze at such low pressures.<ref>Kliore, A. et al. (1965). Occultation Experiment: Results of the First Direct Measurement of Mars's Atmosphere and Ionosphere. ''Science,'' '''149'''(3689), 1243–1248, {{DOI|10.1126/science.149.3689.1243}} PMID 17747455</ref> Thus, a vision of Mars was born of a world much like the Moon but with just a wisp of an atmosphere to blow the dust around. This view of Mars would last nearly another decade until [[Mariner 9]] showed a much more dynamic Mars with hints that the planet’s past environment was more clement than the present one.


===Water in weathering products (aqueous minerals)===
=== Water in weathering products (aqueous minerals) ===
The primary rock type on the surface of Mars is [[basalt]], a fine-grained [[igneous]] rock made up mostly of the [[mafic]] silicate minerals [[olivine]], [[pyroxene]], and [[plagioclase feldspar]].<ref>Soderblom, L.A.; Bell, J.F. (2008). Exploration of the Martian Surface: 1992-2007. In ''The Martian Surface: Composition, Mineralogy, and Physical Properties,'' J.F. Bell, Ed. Cambridge University Press: Cambridge, pp 3-19.</ref> When exposed to water and atmospheric gases, these minerals [[chemical weathering|chemically weather]] into new (secondary) minerals, some of which may incorporate water into their crystalline structures, either as H<sub>2</sub>O or as [[hydroxyl]] (OH). Examples of hydrated (or hydoxylated) minerals include the iron hydroxide [[goethite]] (a common component of terrestrial [[soils]]); the [[evaporate]] minerals [[gypsum]] and [[kieserite]]; [[opal|opalline silica]]; and [[phyllosilicate]]s (also called [[clay minerals]]), such as [[kaolinite]] and [[montmorillonite]]. All of these minerals have been detected on Mars.<ref>Ming, D.W.; Morris, R.V.; Clark, R.C. (2008). Aqueous Alteration on Mars. In ''The Martian Surface: Composition, Mineralogy, and Physical Properties,'' J.F. Bell, Ed. Cambridge University Press: Cambridge, pp 519-540.</ref>
The primary rock type on the surface of Mars is [[basalt]], a fine-grained [[igneous]] rock made up mostly of the [[mafic]] silicate minerals [[olivine]], [[pyroxene]], and [[plagioclase feldspar]].<ref>Soderblom, L.A.; Bell, J.F. (2008). Exploration of the Martian Surface: 1992-2007. In ''The Martian Surface: Composition, Mineralogy, and Physical Properties,'' J.F. Bell, Ed. Cambridge University Press: Cambridge, pp 3-19.</ref> When exposed to water and atmospheric gases, these minerals [[chemical weathering|chemically weather]] into new (secondary) minerals, some of which may incorporate water into their crystalline structures, either as H<sub>2</sub>O or as [[hydroxyl]] (OH). Examples of hydrated (or hydoxylated) minerals include the iron hydroxide [[goethite]] (a common component of terrestrial [[soils]]); the [[evaporate]] minerals [[gypsum]] and [[kieserite]]; [[opal|opalline silica]]; and [[phyllosilicate]]s (also called [[clay minerals]]), such as [[kaolinite]] and [[montmorillonite]]. All of these minerals have been detected on Mars.<ref>Ming, D.W.; Morris, R.V.; Clark, R.C. (2008). Aqueous Alteration on Mars. In ''The Martian Surface: Composition, Mineralogy, and Physical Properties,'' J.F. Bell, Ed. Cambridge University Press: Cambridge, pp 519-540.</ref>
[[File:CRISM Stokes PIA13214.jpg|thumb|right|Minerals identified in [[Stokes (Martian crater)|Stokes crater]] from [[CRISM]] and [[Mars Express|OMEGA]] spectrometers. Green = [[olivine]]; Light blue = [[montmorillonite]]; Red = iron-magnesium phyllosilicate; Dark blue = [[kaolinite]]; Orange = [[pyroxene]].]]
[[File:CRISM Stokes PIA13214.jpg|thumb|right|Minerals identified in [[Stokes (Martian crater)|Stokes crater]] from [[CRISM]] and [[Mars Express|OMEGA]] spectrometers. Green = [[olivine]]; Light blue = [[montmorillonite]]; Red = iron-magnesium phyllosilicate; Dark blue = [[kaolinite]]; Orange = [[pyroxene]].]]
One direct effect of chemical weathering is to consume water and other reactive chemical species, taking them from mobile reservoirs like the [[atmosphere]] and [[hydrosphere]] and sequestering them in rocks and minerals.<ref>Lewis, J.S. (1997). ''Physics and Chemistry of the Solar System,'' revised ed.; Academic Press: San Diego, CA, ISBN 0-12-446742-3.</ref> The amount of water in the Martian crust stored in hydrated minerals is currently unknown, but may be quite large.<ref>Lasue, J. et al. (2013). Quantitative Assessments of the Martian Hydrosphere. ''Space Sci. Rev.,'' '''174''' 155–212, {{DOI|10.1007/s11214-012-9946-5}}</ref> For example, mineralogical models of the rock outcroppings examined by instruments on the [[Opportunity (rover)|''Opportunity'' rover]] at [[Meridiani Planum]] suggest that the [[sulfate mineral|sulfate]] deposits there could contain up to 22% water by weight.<ref>Clark, B.C. et al. (2005). Chemistry and Mineralogy of Outcrops at Meridiani Planum. ''Earth Planet. Sci. Lett.,'' '''240''' 73–94.</ref>
One direct effect of chemical weathering is to consume water and other reactive chemical species, taking them from mobile reservoirs like the [[atmosphere]] and [[hydrosphere]] and sequestering them in rocks and minerals.<ref>Lewis, J.S. (1997). ''Physics and Chemistry of the Solar System,'' revised ed.; Academic Press: San Diego, CA, ISBN 0-12-446742-3.</ref> The amount of water in the Martian crust stored in hydrated minerals is currently unknown, but may be quite large.<ref>Lasue, J. et al. (2013). Quantitative Assessments of the Martian Hydrosphere. ''Space Sci. Rev.,'' '''174''' 155–212, {{DOI|10.1007/s11214-012-9946-5}}</ref> For example, mineralogical models of the rock outcroppings examined by instruments on the [[Opportunity (rover)|''Opportunity'' rover]] at [[Meridiani Planum]] suggest that the [[sulfate mineral|sulfate]] deposits there could contain up to 22% water by weight.<ref>Clark, B.C. et al. (2005). Chemistry and Mineralogy of Outcrops at Meridiani Planum. ''Earth Planet. Sci. Lett.,'' '''240''' 73–94.</ref>


On Earth, all chemical weathering reactions involve water to some degree.<ref>Bloom, A.L. (1978) ''Geomorphology: A Systematic Analysis of Late Cenozoic Landforms;'' Prentice-Hall: Englewood Cliffs, N.J., ISBN 0-13-3530806-8., p. 114.</ref> Thus, many secondary minerals do not actually incorporate water but still require water to form. Some examples of anhydrous secondary minerals include many [[carbonate minerals|carbonates]], some [[sulfate minerals|sulfates]] (e.g., [[anhydrite]]), and metallic oxides such as the iron oxide mineral [[hematite]]. On Mars, a few of these weathering products may theoretically form without water or with scant amounts present as ice or in thin molecular-scale films ([[monolayers]]).<ref>Boynton, W.V. et al. (2009). Evidence for Calcium Carbonate at the Mars Phoenix Landing Site. ''Science,'' '''325''' 61; {{DOI|10.1126/science.1172768}} PMID 19574384</ref><ref>Gooding, J.L.; Arvidson, R.E.; Zolotov, M. YU. (1992). Physical and Chemical Weathering. In ''Mars,'' H.H. Kieffer et al., Eds.; University of Arizona Press: Tucson, AZ, pp. 626–651, ISBN 0-8165-1257-4.</ref> However, the extent to which such exotic weathering processes operate on Mars is still uncertain. Minerals that incorporate water or form in the presence of water are generally termed “aqueous minerals.”
On Earth, all chemical weathering reactions involve water to some degree.<ref>Bloom, A.L. (1978) ''Geomorphology: A Systematic Analysis of Late Cenozoic Landforms;'' Prentice-Hall: Englewood Cliffs, N.J., {{Please check ISBN|0-13-3530806-8}}., p. 114.</ref> Thus, many secondary minerals do not actually incorporate water but still require water to form. Some examples of anhydrous secondary minerals include many [[carbonate minerals|carbonates]], some [[sulfate minerals|sulfates]] (e.g., [[anhydrite]]), and metallic oxides such as the iron oxide mineral [[hematite]]. On Mars, a few of these weathering products may theoretically form without water or with scant amounts present as ice or in thin molecular-scale films ([[monolayers]]).<ref>Boynton, W.V. et al. (2009). Evidence for Calcium Carbonate at the Mars Phoenix Landing Site. ''Science,'' '''325''' 61; {{DOI|10.1126/science.1172768}} PMID 19574384</ref><ref>Gooding, J.L.; Arvidson, R.E.; Zolotov, M. YU. (1992). Physical and Chemical Weathering. In ''Mars,'' H.H. Kieffer et al., Eds.; University of Arizona Press: Tucson, AZ, pp. 626–651, ISBN 0-8165-1257-4.</ref> However, the extent to which such exotic weathering processes operate on Mars is still uncertain. Minerals that incorporate water or form in the presence of water are generally termed “aqueous minerals.”


Aqueous minerals are sensitive indicators of the type of environment that existed when the minerals formed. The ease at which aqueous reactions occur (see [[Gibbs free energy]]) depend on the pressure, temperature, and on the concentrations of the gaseous and soluble species involved.<ref>Melosh, H.J. (2011). ''Planetary Surface Processes;'' Cambridge University Press: Cambridge, UK, ISBN 978-0-521-51418-7., p 296.</ref> Two important properties are [[pH]] and [[reduction potential|oxidation-reduction potential (Eh)]]. For example, the sulfate mineral [[jarosite]] forms only in low pH (highly acidic) water. Phyllosilicates usually form in water of neutral to high pH (alkaline). Eh is a measure is the [[oxidation state]] of an aqueous system. Together Eh and pH indicate the types of minerals that are thermodynamically most likely to form from a given set of aqueous components. Thus, past environmental conditions on Mars, including those conducive to life, can be inferred from the types of minerals present in the rocks.
Aqueous minerals are sensitive indicators of the type of environment that existed when the minerals formed. The ease at which aqueous reactions occur (see [[Gibbs free energy]]) depend on the pressure, temperature, and on the concentrations of the gaseous and soluble species involved.<ref>Melosh, H.J. (2011). ''Planetary Surface Processes;'' Cambridge University Press: Cambridge, UK, ISBN 978-0-521-51418-7., p 296.</ref> Two important properties are [[pH]] and [[reduction potential|oxidation-reduction potential (Eh)]]. For example, the sulfate mineral [[jarosite]] forms only in low pH (highly acidic) water. Phyllosilicates usually form in water of neutral to high pH (alkaline). Eh is a measure is the [[oxidation state]] of an aqueous system. Together Eh and pH indicate the types of minerals that are thermodynamically most likely to form from a given set of aqueous components. Thus, past environmental conditions on Mars, including those conducive to life, can be inferred from the types of minerals present in the rocks.


===Hydrothermal alteration===
=== Hydrothermal alteration ===
Aqueous minerals can also form in the subsurface by [[hydrothermal]] fluids migrating through pores and fissures. The heat source driving a hydrothermal system may be nearby [[magma]] bodies or residual heat from large [[impact crater|impacts]].<ref>Abramov, O.; Kring, D.A. (2005). Impact-Induced Hydrothermal Activity on Early Mars. ''J. Geophys. Res.,'' '''110''' E12S09, {{DOI|10.1029/2005JE002453}}</ref> One important type of hydrothermal alteration in the Earth’s oceanic crust is [[serpentinite|serpentinization]], which occurs when seawater migrates through [[ultramafic]] and basaltic rocks. The water-rock reactions result in the oxidation of ferrous iron in olivine and pyroxene to produce ferric iron (as the mineral [[magnetite]]) yielding molecular [[hydrogen]] (H<sub>2</sub>) as a byproduct. The process creates a highly alkaline and reducing (low Eh) environment favoring the formation of certain phyllosilicates (serpentine minerals) and various carbonate minerals, which together form a rock called [[serpentinite]].<ref>Schrenk, M.O.; Brazelton, W,J.; Lang, S.Q. (2013). Serpentinization, Carbon, and Deep Life. ''Reviews in Mineralogy & Geochemistry,'' '''75''' 575–606, {{DOI|10.2138/rmg.2013.75.18}}</ref> The hydrogen gas produced can be an important energy source for [[chemosynthesis|chemosynthtetic]] organisms or it can react with CO<sub>2</sub> to produce [[methane]] gas, a process that has been considered as a non-biological source for the trace amounts of methane reported in the Martian atmosphere.<ref>Baucom, Martin (2006). Life on Mars? ''American Scientist,'' March–April. http://www.americanscientist.org/issues/pub/life-on-mars</ref> Serpentine minerals can also store a lot of water (as hydroxyl) in their crystal structure. A recent study has argued that hypothetical serpentinites in the ancient highland crust of Mars could hold as much as a 500-meter-thick global equivalent layer (GEL) of water.<ref>Chassefière, E; Langlais, B; Quesnel, Y; Leblanc, F. (2013). The Fate of Early Mars’ Lost Water: The Role of Serpentinization. ''EPSC Abstracts,'' '''8''' EPSC2013-188. http://meetingorganizer.copernicus.org/EPSC2013/EPSC2013-188.pdf</ref> Although some serpentine minerals have been detected on Mars, no widespread outcroppings are evident from remote sensing data.<ref>Ehlmann, B. L.; Mustard, J.F.; Murchie, S.L. (2010). Geologic Setting of Serpentine Deposits on Mars. ''Geophys. Res. Lett.,'' '''37''' L06201, {{DOI|10.1029/2010GL042596}}</ref> However, this fact does not preclude the presence of large amounts of sepentinite hidden at depth in the Martian crust.
Aqueous minerals can also form in the subsurface by [[hydrothermal]] fluids migrating through pores and fissures. The heat source driving a hydrothermal system may be nearby [[magma]] bodies or residual heat from large [[impact crater|impacts]].<ref>Abramov, O.; Kring, D.A. (2005). Impact-Induced Hydrothermal Activity on Early Mars. ''J. Geophys. Res.,'' '''110''' E12S09, {{DOI|10.1029/2005JE002453}}</ref> One important type of hydrothermal alteration in the Earth’s oceanic crust is [[serpentinite|serpentinization]], which occurs when seawater migrates through [[ultramafic]] and basaltic rocks. The water-rock reactions result in the oxidation of ferrous iron in olivine and pyroxene to produce ferric iron (as the mineral [[magnetite]]) yielding molecular [[hydrogen]] (H<sub>2</sub>) as a byproduct. The process creates a highly alkaline and reducing (low Eh) environment favoring the formation of certain phyllosilicates (serpentine minerals) and various carbonate minerals, which together form a rock called [[serpentinite]].<ref>Schrenk, M.O.; Brazelton, W,J.; Lang, S.Q. (2013). Serpentinization, Carbon, and Deep Life. ''Reviews in Mineralogy & Geochemistry,'' '''75''' 575–606, {{DOI|10.2138/rmg.2013.75.18}}</ref> The hydrogen gas produced can be an important energy source for [[chemosynthesis|chemosynthtetic]] organisms or it can react with CO<sub>2</sub> to produce [[methane]] gas, a process that has been considered as a non-biological source for the trace amounts of methane reported in the Martian atmosphere.<ref>Baucom, Martin (2006). Life on Mars? ''American Scientist,'' March–April. http://www.americanscientist.org/issues/pub/life-on-mars</ref> Serpentine minerals can also store a lot of water (as hydroxyl) in their crystal structure. A recent study has argued that hypothetical serpentinites in the ancient highland crust of Mars could hold as much as a 500-meter-thick global equivalent layer (GEL) of water.<ref>Chassefière, E; Langlais, B; Quesnel, Y; Leblanc, F. (2013). The Fate of Early Mars’ Lost Water: The Role of Serpentinization. ''EPSC Abstracts,'' '''8''' EPSC2013-188. http://meetingorganizer.copernicus.org/EPSC2013/EPSC2013-188.pdf</ref> Although some serpentine minerals have been detected on Mars, no widespread outcroppings are evident from remote sensing data.<ref>Ehlmann, B. L.; Mustard, J.F.; Murchie, S.L. (2010). Geologic Setting of Serpentine Deposits on Mars. ''Geophys. Res. Lett.,'' '''37''' L06201, {{DOI|10.1029/2010GL042596}}</ref> However, this fact does not preclude the presence of large amounts of sepentinite hidden at depth in the Martian crust.


===Weathering rates===
=== Weathering rates ===
The rates at which primary minerals convert to secondary aqueous minerals vary. Primary silicate minerals crystallize from magma under pressures and temperatures vastly higher than conditions at the surface of a planet. When exposed to a surface environment these minerals are out of [[chemical equilibrium|equilibrium]] and will tend to interact with available chemical components to form more stable mineral phases. In general, the silicate minerals that crystallize at the highest temperatures (solidify first in a cooling magma) weather the most rapidly.<ref>Bloom, A.L. (1978) ''Geomorphology: A Systematic Analysis of Late Cenozoic Landforms;'' Prentice-Hall: Englewood Cliffs, N.J., ISBN 0-13-3530806-8., p. 120</ref> On the Earth and Mars, the most common mineral to meet this criterion is [[olivine]], which readily weathers to [[clay minerals]] in the presence of water.
The rates at which primary minerals convert to secondary aqueous minerals vary. Primary silicate minerals crystallize from magma under pressures and temperatures vastly higher than conditions at the surface of a planet. When exposed to a surface environment these minerals are out of [[chemical equilibrium|equilibrium]] and will tend to interact with available chemical components to form more stable mineral phases. In general, the silicate minerals that crystallize at the highest temperatures (solidify first in a cooling magma) weather the most rapidly.<ref>Bloom, A.L. (1978) ''Geomorphology: A Systematic Analysis of Late Cenozoic Landforms;'' Prentice-Hall: Englewood Cliffs, N.J., {{Please check ISBN|0-13-3530806-8}}., p. 120</ref> On the Earth and Mars, the most common mineral to meet this criterion is [[olivine]], which readily weathers to [[clay minerals]] in the presence of water.


Despite this, the mineral [[olivine]] is widespread on Mars,<ref>Ody, A. et al. (2013). Global Investigation of Olivine on Mars: Insights into Crust and Mantle Compositions. ''J. Geophys. Res.,'' '''118''' 234–262, {{DOI|10.1029/2012JE004149}}</ref> indicating that Mars' surface has not been pervasively altered by water. Nevertheless, abundant geological evidence suggests otherwise.<ref>{{cite journal |title=Noble Gases in Iddingsite from the Lafayette meteorite: Evidence for Liquid water on Mars in the last few hundred million years |journal=Meteoritics and Planetary Science |volume=35 |issue=1 |pages=107–115 |year=2000 |doi=10.1111/j.1945-5100.2000.tb01978.x |last1=Swindle |first1=T. D. |last2=Treiman |first2=A. H. |last3=Lindstrom |first3=D. J. |last4=Burkland |first4=M. K. |last5=Cohen |first5=B. A. |last6=Grier |first6=J. A. |last7=Li |first7=B. |last8=Olson |first8=E. K. |bibcode = 2000M&PS...35..107S }}</ref><ref>{{cite journal | doi = 10.1038/341514a0 | last1 = Gulick | first1 = V. | last2 = Baker | first2 = V. | author-separator =, | author-name-separator= | year = 1989 | title = Fluvial valleys and martian palaeoclimates | url = | journal=Nature | volume = 341 | issue = 6242| pages = 514–516 |bibcode = 1989Natur.341..514G }}</ref><ref>{{cite journal | last1=Head |first1= J. |year= 2001 |title= Water in Middle Mars History: New Insights From MOLA Data | journal=American Geophysical Union | bibcode = 2001AGUSM...P31A02H | last2=Kreslavsky | first2=M. A. | last3=Ivanov | first3=M. A. | last4=Hiesinger | first4=H. | last5=Fuller | first5=E. R. | last6=Pratt | first6=S. }}</ref><ref>{{cite journal | last1=Head |first1= J. ''et al.'' |year= 2001 |title= Exploration for standing Bodies of Water on Mars: When Were They There, Where did They go, and What are the Implications for Astrobiology? | bibcode = 2001AGUFM.P21C..03H | journal=American Geophysical Union | volume=21 | page=03 }}</ref><ref>{{cite web|url=http://www.space.com/707-mars-rover-meteorite-discovery-triggers-questions.html |title=Mars Rover's Meteorite Discovery Triggers Questions |publisher=Space.com |date= |accessdate=2013-02-10}}</ref>
Despite this, the mineral [[olivine]] is widespread on Mars,<ref>Ody, A. et al. (2013). Global Investigation of Olivine on Mars: Insights into Crust and Mantle Compositions. ''J. Geophys. Res.,'' '''118''' 234–262, {{DOI|10.1029/2012JE004149}}</ref> indicating that Mars' surface has not been pervasively altered by water. Nevertheless, abundant geological evidence suggests otherwise.<ref>{{cite journal |title=Noble Gases in Iddingsite from the Lafayette meteorite: Evidence for Liquid water on Mars in the last few hundred million years |journal=Meteoritics and Planetary Science |volume=35 |issue=1 |pages=107–115 |year=2000 |doi=10.1111/j.1945-5100.2000.tb01978.x |last1=Swindle |first1=T. D. |last2=Treiman |first2=A. H. |last3=Lindstrom |first3=D. J. |last4=Burkland |first4=M. K. |last5=Cohen |first5=B. A. |last6=Grier |first6=J. A. |last7=Li |first7=B. |last8=Olson |first8=E. K. |bibcode = 2000M&PS...35..107S }}</ref><ref>{{cite journal | doi = 10.1038/341514a0 | last1 = Gulick | first1 = V. | last2 = Baker | first2 = V. | author-separator =, | author-name-separator= | year = 1989 | title = Fluvial valleys and martian palaeoclimates | url = | journal=Nature | volume = 341 | issue = 6242| pages = 514–516 |bibcode = 1989Natur.341..514G }}</ref><ref>{{cite journal | last1=Head |first1= J. |year= 2001 |title= Water in Middle Mars History: New Insights From MOLA Data | journal=American Geophysical Union | bibcode = 2001AGUSM...P31A02H | last2=Kreslavsky | first2=M. A. | last3=Ivanov | first3=M. A. | last4=Hiesinger | first4=H. | last5=Fuller | first5=E. R. | last6=Pratt | first6=S. }}</ref><ref>{{cite journal | last1=Head |first1= J. ''et al.'' |year= 2001 |title= Exploration for standing Bodies of Water on Mars: When Were They There, Where did They go, and What are the Implications for Astrobiology? | bibcode = 2001AGUFM.P21C..03H | journal=American Geophysical Union | volume=21 | page=03 }}</ref><ref>{{cite web|url=http://www.space.com/707-mars-rover-meteorite-discovery-triggers-questions.html |title=Mars Rover's Meteorite Discovery Triggers Questions |publisher=Space.com |date= |accessdate=2013-02-10}}</ref>
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By 1979 it was thought that [[outflow channels]] formed in single, catastrophic ruptures of subsurface water reservoirs, possibly sealed by ice, discharging colossal quantities of water across an otherwise arid Mars surface.<ref>{{cite journal | last1 = Carr | first1 = M.H. | year = 1979 | title = Formation of Martian flood features by relaease of water from confined aquifers | url = http://www.es.ucsc.edu/~rcoe/eart206/Carr_MarsFloodFeatures_JGR79.pdf| journal = J. Geophys. Res. | volume = 84 | issue = | pages = 2995–3007 |bibcode = 1979JGR....84.2995C |doi = 10.1029/JB084iB06p02995 }}</ref><ref>{{cite journal | doi = 10.1016/0019-1035(74)90101-8 | last1 = Baker | first1 = V. | last2 = Milton | first2 = D. | author-separator =, | author-name-separator= | year = 1974 | title = Erosion by Catastrophic Floods on Mars and Earth | url = | journal=Icarus | volume = 23 | pages = 27–41 | bibcode=1974Icar...23...27B}}</ref> In addition, evidence in favor of heavy or even catastrophic flooding is found in the [[Giant current ripples|giant ripples]] in the [[Athabasca Vallis]].<ref>{{cite web|url=http://www.msss.com/mars_images/moc/2004/09/27/ |title=Mars Global Surveyor MOC2-862 Release |publisher=Msss.com |date= |accessdate=2012-01-16}}</ref><ref name="DOInature">{{cite journal | doi = 10.1038/nature05594 | title = Meridiani Planum and the global hydrology of Mars | year = 2007 | last1 = Andrews-Hanna | first1 = Jeffrey C. | last2 = Phillips | first2 = Roger J. | last3 = Zuber | first3 = Maria T. | journal = Nature | volume = 446 | issue = 7132 | pages = 163–6 | pmid = 17344848 |bibcode = 2007Natur.446..163A }}</ref> Many outflow channels begin at [[Martian chaos terrain|Chaos]] or [[Chasma]] features, providing evidence for the rupture that could have breached a subsurface ice seal.<ref name="Carr" />
By 1979 it was thought that [[outflow channels]] formed in single, catastrophic ruptures of subsurface water reservoirs, possibly sealed by ice, discharging colossal quantities of water across an otherwise arid Mars surface.<ref>{{cite journal | last1 = Carr | first1 = M.H. | year = 1979 | title = Formation of Martian flood features by relaease of water from confined aquifers | url = http://www.es.ucsc.edu/~rcoe/eart206/Carr_MarsFloodFeatures_JGR79.pdf| journal = J. Geophys. Res. | volume = 84 | issue = | pages = 2995–3007 |bibcode = 1979JGR....84.2995C |doi = 10.1029/JB084iB06p02995 }}</ref><ref>{{cite journal | doi = 10.1016/0019-1035(74)90101-8 | last1 = Baker | first1 = V. | last2 = Milton | first2 = D. | author-separator =, | author-name-separator= | year = 1974 | title = Erosion by Catastrophic Floods on Mars and Earth | url = | journal=Icarus | volume = 23 | pages = 27–41 | bibcode=1974Icar...23...27B}}</ref> In addition, evidence in favor of heavy or even catastrophic flooding is found in the [[Giant current ripples|giant ripples]] in the [[Athabasca Vallis]].<ref>{{cite web|url=http://www.msss.com/mars_images/moc/2004/09/27/ |title=Mars Global Surveyor MOC2-862 Release |publisher=Msss.com |date= |accessdate=2012-01-16}}</ref><ref name="DOInature">{{cite journal | doi = 10.1038/nature05594 | title = Meridiani Planum and the global hydrology of Mars | year = 2007 | last1 = Andrews-Hanna | first1 = Jeffrey C. | last2 = Phillips | first2 = Roger J. | last3 = Zuber | first3 = Maria T. | journal = Nature | volume = 446 | issue = 7132 | pages = 163–6 | pmid = 17344848 |bibcode = 2007Natur.446..163A }}</ref> Many outflow channels begin at [[Martian chaos terrain|Chaos]] or [[Chasma]] features, providing evidence for the rupture that could have breached a subsurface ice seal.<ref name="Carr" />


The branching [[Valley networks (Mars)|valley networks]] of Mars are not however consistent with formation by sudden catastrophic release of groundwater, both in terms of their dendritic shapes which do not come from a single outflow point, and in terms of the discharges which apparently flowed along them.<ref>Irwin, Rossman P., Robert A. Craddock, and Alan D. Howard. "Interior channels in Martian valley networks: Discharge and runoff production." Geology 33.6 (2005) 489-492.</ref> Instead, some authors have argued that they were formed by slow seepage of groundwater from the subsurface essentially as springs.<ref name="Jakosky1999">{{cite journal| last=Jakosky| first=Bruce M.| authorlink=|year =1999|month=|title=Water, Climate, and Life| journal=Science| volume=283| issue=5402| pages=648–649| doi=10.1126/science.283.5402.648|url=| accessdate=| quote=| pmid=9988657 }}</ref> In support of this interpretation, the upstream ends of many valleys in such networks begin with [[box canyon]] or "amphitheater" heads, which on Earth are typically associated with groundwater seepage. There is also little evidence of finer scale channels or valleys at the tips of the channels, which some authors have interpreted as showing the flow appeared suddenly from the subsurface with appreciable discharge, rather than accumulating gradually across the surface.<ref name ="Carr" /> However, others have disputed the strong link between amphitheater heads of valleys and formation by groundwater for terrestrial examples,<ref>Lamb, Michael P., et al. "Can springs cut canyons into rock?." Journal of Geophysical Research: Planets (1991–2012) 111.E7 (2006).</ref> and have argued that the lack of fine scale heads to valley networks is due to their removal by [[weathering]] or [[impact gardening]].<ref name="Carr" /> Most authors however accept that most valley networks are at least partly influenced and shaped by groundwater seep processes.
The branching [[Valley networks (Mars)|valley networks]] of Mars are not however consistent with formation by sudden catastrophic release of groundwater, both in terms of their dendritic shapes which do not come from a single outflow point, and in terms of the discharges which apparently flowed along them.<ref>Irwin, Rossman P., Robert A. Craddock, and Alan D. Howard. "Interior channels in Martian valley networks: Discharge and runoff production." Geology 33.6 (2005) 489-492.</ref> Instead, some authors have argued that they were formed by slow seepage of groundwater from the subsurface essentially as springs.<ref name="Jakosky1999">{{cite journal| last=Jakosky| first=Bruce M.| authorlink=|date= 1999|title=Water, Climate, and Life| journal=Science| volume=283| issue=5402| pages=648–649| doi=10.1126/science.283.5402.648|url=| accessdate=| quote=| pmid=9988657 }}</ref> In support of this interpretation, the upstream ends of many valleys in such networks begin with [[box canyon]] or "amphitheater" heads, which on Earth are typically associated with groundwater seepage. There is also little evidence of finer scale channels or valleys at the tips of the channels, which some authors have interpreted as showing the flow appeared suddenly from the subsurface with appreciable discharge, rather than accumulating gradually across the surface.<ref name ="Carr" /> However, others have disputed the strong link between amphitheater heads of valleys and formation by groundwater for terrestrial examples,<ref>Lamb, Michael P., et al. "Can springs cut canyons into rock?." Journal of Geophysical Research: Planets (1991–2012) 111.E7 (2006).</ref> and have argued that the lack of fine scale heads to valley networks is due to their removal by [[weathering]] or [[impact gardening]].<ref name="Carr" /> Most authors however accept that most valley networks are at least partly influenced and shaped by groundwater seep processes.


[[File:Burns cliff.jpg|thumb|right|The preservation and cementation of aeolian dune [[stratigraphy]] in Burns Cliff in [[Endurance (crater)|Endurance Crater]] are thought to have been controlled by flow of shallow groundwater.<ref name="BurnsCliff">J.P. Grotzinger, R.E. Arvidson, J.F. Bell III, W. Calvin, B.C. Clark, D.A. Fike, M. Golombek, R. Greeley, A. Haldemann, K.E. Herkenhoff, B.L. Jolliff, A.H. Knoll, M. Malin, S.M. McLennan, T. Parker, L. Soderblom, J.N. Sohl-Dickstein, S.W. Squyres, N.J. Tosca, W.A. Watters, Stratigraphy and sedimentology of a dry to wet eolian depositional system, Burns formation, Meridiani Planum, Mars, Earth and Planetary Science Letters, Volume 240, Issue 1, 30 November 2005, Pages 11-72, ISSN 0012-821X, http://dx.doi.org/10.1016/j.epsl.2005.09.039. (http://www.sciencedirect.com/science/article/pii/S0012821X05006333)</ref>]]
[[File:Burns cliff.jpg|thumb|right|The preservation and cementation of aeolian dune [[stratigraphy]] in Burns Cliff in [[Endurance (crater)|Endurance Crater]] are thought to have been controlled by flow of shallow groundwater.<ref name="BurnsCliff">J.P. Grotzinger, R.E. Arvidson, J.F. Bell III, W. Calvin, B.C. Clark, D.A. Fike, M. Golombek, R. Greeley, A. Haldemann, K.E. Herkenhoff, B.L. Jolliff, A.H. Knoll, M. Malin, S.M. McLennan, T. Parker, L. Soderblom, J.N. Sohl-Dickstein, S.W. Squyres, N.J. Tosca, W.A. Watters, Stratigraphy and sedimentology of a dry to wet eolian depositional system, Burns formation, Meridiani Planum, Mars, Earth and Planetary Science Letters, Volume 240, Issue 1, 30 November 2005, Pages 11-72, ISSN 0012-821X, http://dx.doi.org/10.1016/j.epsl.2005.09.039. (http://www.sciencedirect.com/science/article/pii/S0012821X05006333)</ref>]]
[[Groundwater]] also plays a vital role in controlling broad scale sedimentation patterns and processes on Mars<ref name='Michalski'>{{cite journal | title = Groundwater activity on Mars and implications for a deep biosphere | journal = Nature Geoscience | date = 20 January 2013 | first = Joseph R. Michalski | coauthors = Paul B. Niles, Javier Cuadros, John Parnell, A. Deanne Rogers, Shawn P. Wright | volume = 6 | pages = 133–138 | doi = 10.1038/ngeo1706 | url = http://www.nature.com/ngeo/journal/v6/n2/full/ngeo1706.html | accessdate = 2013-06-17 | quote = Here we present a conceptual model of subsurface habitability of Mars and evaluate evidence for groundwater upwelling in deep basins.|bibcode = 2013NatGe...6..133M | issue=2}}</ref> According to this hypothesis, groundwater with dissolved minerals came to the surface, in and around craters, and helped to form layers by adding minerals —especially sulfate— and [[Clastic sediment#Cementation|cementing sediments]].<ref name=Zuber /><ref>Andrews‐Hanna, J. C., M. T. Zuber, R. E. Arvidson, and S. M. Wiseman (2010), Early Mars hydrology: Meridiani playa deposits and the sedimentary record of Arabia Terra, J. Geophys. Res., 115, E06002, {{DOI|10.1029/2009JE003485}}.</ref><ref>Grotzinger, J. P., et al. (2005), Stratigraphy and sedimentology of a dry to wet eolian depositional system, Burns formation, Meridiani Planum, Mars, Earth Planet. Sci. Lett., 240, 11–72, {{DOI|10.1016/j.epsl.2005.09.039}}</ref><ref>McLennan, S. M., et al. (2005), Provenance and diagenesis of the evaporitebearing Burns formation, Meridiani Planum, Mars, Earth Planet. Sci. Lett., 240, 95–121, {{DOI|10.1016/j.epsl.2005.09.041}}</ref><ref>Squyres, S. W., and A. H. Knoll (2005), Sedimentary rocks at Meridiani Planum: Origin, diagenesis, and implications for life on Mars, Earth Planet. Sci. Lett., 240, 1–10, {{DOI|10.1016/j.epsl.2005.09.038}}.</ref><ref>Squyres, S. W., et al. (2006), Two years at Meridiani Planum: Results from the Opportunity rover, ''Science'', 313, 1403–1407, {{DOI|10.1126/science}}.</ref> In other words, some layers may be formed by groundwater rising up depositing minerals and cementing existing, loose, [[Aeolian processes|aeolian]] sediments. The hardened layers are consequently more protected from [[erosion]]. This process may occur instead of layers forming under lakes. A study published in 2011 using data from the [[Mars Reconnaissance Orbiter]], show that the same kinds of sediments exist in a large area that includes [[Arabia Terra]].<ref>M. Wiseman, J. C. Andrews-Hanna, R. E. Arvidson, J. F. Mustard, K. J. Zabrusky. "Distribution of Hydrated Sulfates Across Arabia Terra Using CRISM Data: Implications for Martian Hydrology". 42nd Lunar and Planetary Science Conference (2011) 2133.pdf</ref> It has been argued that areas which we know from satellite remote sensing are rich in sedimentary rocks are also those areas which are most likely to experience groundwater upwelling on a regional scale.<ref>Andrews‐Hanna, Jeffrey C., and Kevin W. Lewis. "Early Mars hydrology: 2. Hydrological evolution in the Noachian and Hesperian epochs." Journal of Geophysical Research: Planets (1991–2012) 116.E2 (2011).</ref>
[[Groundwater]] also plays a vital role in controlling broad scale sedimentation patterns and processes on Mars<ref name='Michalski'>{{cite journal | title = Groundwater activity on Mars and implications for a deep biosphere | journal = Nature Geoscience | date = 20 January 2013 | first = Joseph R.|last= Michalski |first2=Paul B.|last2=Niles|first3=Javier|last3=Cuadros|first4=John|last4=Parnell|first5=A. Deanne|last5=Rogers|first6=Shawn P.|last6=Wright| volume = 6 | pages = 133–138 | doi = 10.1038/ngeo1706 | url = http://www.nature.com/ngeo/journal/v6/n2/full/ngeo1706.html | accessdate = 2013-06-17 | quote = Here we present a conceptual model of subsurface habitability of Mars and evaluate evidence for groundwater upwelling in deep basins.|bibcode = 2013NatGe...6..133M | issue=2}}</ref> According to this hypothesis, groundwater with dissolved minerals came to the surface, in and around craters, and helped to form layers by adding minerals —especially sulfate— and [[Clastic sediment#Cementation|cementing sediments]].<ref name=Zuber /><ref>Andrews‐Hanna, J. C., M. T. Zuber, R. E. Arvidson, and S. M. Wiseman (2010), Early Mars hydrology: Meridiani playa deposits and the sedimentary record of Arabia Terra, J. Geophys. Res., 115, E06002, {{DOI|10.1029/2009JE003485}}.</ref><ref>Grotzinger, J. P., et al. (2005), Stratigraphy and sedimentology of a dry to wet eolian depositional system, Burns formation, Meridiani Planum, Mars, Earth Planet. Sci. Lett., 240, 11–72, {{DOI|10.1016/j.epsl.2005.09.039}}</ref><ref>McLennan, S. M., et al. (2005), Provenance and diagenesis of the evaporitebearing Burns formation, Meridiani Planum, Mars, Earth Planet. Sci. Lett., 240, 95–121, {{DOI|10.1016/j.epsl.2005.09.041}}</ref><ref>Squyres, S. W., and A. H. Knoll (2005), Sedimentary rocks at Meridiani Planum: Origin, diagenesis, and implications for life on Mars, Earth Planet. Sci. Lett., 240, 1–10, {{DOI|10.1016/j.epsl.2005.09.038}}.</ref><ref>Squyres, S. W., et al. (2006), Two years at Meridiani Planum: Results from the Opportunity rover, ''Science'', 313, 1403–1407, {{DOI|10.1126/science}}.</ref> In other words, some layers may be formed by groundwater rising up depositing minerals and cementing existing, loose, [[Aeolian processes|aeolian]] sediments. The hardened layers are consequently more protected from [[erosion]]. This process may occur instead of layers forming under lakes. A study published in 2011 using data from the [[Mars Reconnaissance Orbiter]], show that the same kinds of sediments exist in a large area that includes [[Arabia Terra]].<ref>M. Wiseman, J. C. Andrews-Hanna, R. E. Arvidson, J. F. Mustard, K. J. Zabrusky. "Distribution of Hydrated Sulfates Across Arabia Terra Using CRISM Data: Implications for Martian Hydrology". 42nd Lunar and Planetary Science Conference (2011) 2133.pdf</ref> It has been argued that areas which we know from satellite remote sensing are rich in sedimentary rocks are also those areas which are most likely to experience groundwater upwelling on a regional scale.<ref>Andrews‐Hanna, Jeffrey C., and Kevin W. Lewis. "Early Mars hydrology: 2. Hydrological evolution in the Noachian and Hesperian epochs." Journal of Geophysical Research: Planets (1991–2012) 116.E2 (2011).</ref>


=== Mars Ocean Hypothesis ===
=== Mars Ocean Hypothesis ===
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| image2 = Water equivalent hydrogen abundance in the high latitudes of Mars.jpg
| image2 = Water equivalent hydrogen abundance in the high latitudes of Mars.jpg
| caption2 = Proportion of water ice present in the upper meter of the Martian surface for lower (top) and higher (bottom) latitudes. The percentages are derived through stoichiometric calculations based on epithermal neutron fluxes. These fluxes were detected by the Neutron Spectrometer aboard the 2001 Mars Odyssey spacecraft.}}
| caption2 = Proportion of water ice present in the upper meter of the Martian surface for lower (top) and higher (bottom) latitudes. The percentages are derived through stoichiometric calculations based on epithermal neutron fluxes. These fluxes were detected by the Neutron Spectrometer aboard the 2001 Mars Odyssey spacecraft.}}
A significant amount of surface [[hydrogen]] has been observed globally by the [[Mars Odyssey]] Neutron Spectrometer and [[Gamma Ray Spectrometer]].<ref name = Boynton2007>Boynton, W. V. et al. (2007), Concentration of H, Si, Cl, K, Fe, and Th in the low and mid latitude regions of Mars, [[Journal of Geophysical Research]] Planets, in press [http://dx.doi.org/10.1029/2007JE002887 {{DOI|10.1029/2007JE002887]}}</ref> This hydrogen is thought to be incorporated into the molecular structure of ice, and through [[stoichiometry|stoichiometric]] calculations the observed fluxes have been converted into concentrations of water ice in the upper meter of the Martian surface. This process has revealed that ice is both widespread and abundant on the modern surface. Below 60 degrees of latitude, ice is concentrated in several regional patches, particularly around the [[Elysium Mons|Elysium]] volcanoes, [[Terra Sabaea]], and northwest of [[Terra Sirenum]], and exists in concentrations up to 18% ice in the subsurface. However, above 60 degrees latitude, ice is highly abundant. Polewards on 70 degrees of latitude, ice concentrations exceed 25% almost everywhere, and approach 100% at the poles.<ref>Feldman, W. C., Prettyman, T. H., Maurice, S., Plaut, J. J., Bish, D. L., Vaniman, D. T., & Tokar, R. L. (2004). Global distribution of near-surface hydrogen on Mars. Journal of Geophysical Research, 109(E9), E09006, {{DOI|10.1029/2003JE002160}}</ref> More recently, the [[SHARAD]] and [[MARSIS]] radar sounding instruments have begun to be able to confirm whether individual surface features are ice rich. Due to the known instability of ice at current Martian surface conditions, it is thought that almost all of this ice must be covered by a veneer of rocky or dusty material.
A significant amount of surface [[hydrogen]] has been observed globally by the [[Mars Odyssey]] Neutron Spectrometer and [[Gamma Ray Spectrometer]].<ref name = Boynton2007>Boynton, W. V. et al. (2007), Concentration of H, Si, Cl, K, Fe, and Th in the low and mid latitude regions of Mars, [[Journal of Geophysical Research]] Planets, in press [http://dx.doi.org/10.1029/2007JE002887 {{DOI|10.1029/2007JE002887]}}</ref> This hydrogen is thought to be incorporated into the molecular structure of ice, and through [[stoichiometry|stoichiometric]] calculations the observed fluxes have been converted into concentrations of water ice in the upper meter of the Martian surface. This process has revealed that ice is both widespread and abundant on the modern surface. Below 60 degrees of latitude, ice is concentrated in several regional patches, particularly around the [[Elysium Mons|Elysium]] volcanoes, [[Terra Sabaea]], and northwest of [[Terra Sirenum]], and exists in concentrations up to 18% ice in the subsurface. However, above 60 degrees latitude, ice is highly abundant. Polewards on 70 degrees of latitude, ice concentrations exceed 25% almost everywhere, and approach 100% at the poles.<ref>Feldman, W. C., Prettyman, T. H., Maurice, S., Plaut, J. J., Bish, D. L., Vaniman, D. T., ... & Tokar, R. L. (2004). Global distribution of near-surface hydrogen on Mars. Journal of Geophysical Research, 109(E9), E09006, {{DOI|10.1029/2003JE002160}}</ref> More recently, the [[SHARAD]] and [[MARSIS]] radar sounding instruments have begun to be able to confirm whether individual surface features are ice rich. Due to the known instability of ice at current Martian surface conditions, it is thought that almost all of this ice must be covered by a veneer of rocky or dusty material.


The Mars Odyssey neutron spectrometer observations indicate that if all the ice in the top meter of the Martian surface were spread evenly, it would give a Water Equivalent Global layer (WEG) of at least ~14&nbsp;cm—in other words, the globally averaged Martian surface is approximately 14% water.<ref name = Feldman2004>Feldman, W. C. et al. (2004), [http://dx.doi.org/10.1029/2003JE002160 {{DOI|10.1029/2003JE002160]}}</ref> The water ice currently locked in both Martian poles corresponds to a WEG of 30&nbsp;m, and geomorphic evidence favors significantly larger quantities of [[surface water]] over geologic history, with WEG as deep as 500&nbsp;m.<ref name = Feldman2004 /> It is believed that part of this past water has been lost to the deep subsurface, and part to space, although the detailed mass balance of these processes remains poorly understood.<ref name="Carr" /> The current atmospheric reservoir of water is important as a conduit allowing gradual migration of ice from one part of the surface to another on both seasonal and longer timescales. However, it is insignificant in volume, with a WEG of no more than 10&nbsp;µm.<ref name = Feldman2004 />
The Mars Odyssey neutron spectrometer observations indicate that if all the ice in the top meter of the Martian surface were spread evenly, it would give a Water Equivalent Global layer (WEG) of at least ~14&nbsp;cm—in other words, the globally averaged Martian surface is approximately 14% water.<ref name = Feldman2004>Feldman, W. C. et al. (2004), [http://dx.doi.org/10.1029/2003JE002160 {{DOI|10.1029/2003JE002160]}}</ref> The water ice currently locked in both Martian poles corresponds to a WEG of 30&nbsp;m, and geomorphic evidence favors significantly larger quantities of [[surface water]] over geologic history, with WEG as deep as 500&nbsp;m.<ref name = Feldman2004 /> It is believed that part of this past water has been lost to the deep subsurface, and part to space, although the detailed mass balance of these processes remains poorly understood.<ref name="Carr" /> The current atmospheric reservoir of water is important as a conduit allowing gradual migration of ice from one part of the surface to another on both seasonal and longer timescales. However, it is insignificant in volume, with a WEG of no more than 10&nbsp;µm.<ref name = Feldman2004 />
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=== Equatorial frozen sea ===
=== Equatorial frozen sea ===
Surface features consistent with existing [[pack ice]] have been discovered in the southern [[Elysium Planitia]].<ref name="Cabrol, N 2010">Cabrol, N. and E. Grin (eds.). 2010. Lakes on Mars. Elsevier. NY</ref> What appear to be plates of broken ice, ranging in size from 30&nbsp;m to 30&nbsp;km, are found in channels leading to a flooded area of approximately the same depth and width as the [[North Sea]]. The plates show signs of break up and rotation that clearly distinguish them from lava plates elsewhere on the surface of Mars. The source for the flood is thought to be the nearby geological fault [[Cerberus Fossae]] which spewed water as well as lava aged some 2 to 10 million years. It was suggested that the water exited the [[Cerberus Fossae]] then pooled and froze in the low, level plains and that such lakes may still exist.<ref name="Murray2007">{{cite journal|last=Murray |first=John B. |coauthors=''et al.'' |year=2005 |title=Evidence from the Mars Express High Resolution Stereo Camera for a frozen sea close to Mars' equator |journal=Nature |pmid=15772653 |volume=434 |issue= 7031|pages=352–356 |doi=10.1038/nature03379 |url=http://www.nature.com/nature/journal/v434/n7031/abs/nature03379.html |quote= Here we present High Resolution Stereo Camera images from the European Space Agency Mars Express spacecraft that indicate that such lakes may still exist. |bibcode = 2005Natur.434..352M }}</ref> Not all scientists agree with these conclusions.<ref name="Carr" /><ref>{{cite journal | last1=Orosei | first1=R. | last2=Cartacci | first2=M. | last3=Cicchetti | first3=A. | last4=Noschese | first4=R. | last5=Federico | first5=C. | last6=Frigeri | first6=A. | last7=Flamini | first7=E. | last8=Holt | first8=J. W. | last9=Marinangeli | first9=L. | title=Radar subsurface sounding over the putative frozen sea in Cerberus Palus, Mars | url=http://www.lpi.usra.edu/meetings/lpsc2008/pdf/1866.pdf | format=PDF | bibcode = 2007AGUFM.P14B..05O | doi = 10.1109/ICGPR.2010.5550143 |volume= XXXIX | journal=Lunar and Planetary Science | page=1 |year=2008 | isbn=978-1-4244-4604-9}}</ref><ref>ISBN 978-0-521-85226-5</ref>
Surface features consistent with existing [[pack ice]] have been discovered in the southern [[Elysium Planitia]].<ref name="Cabrol, N 2010">Cabrol, N. and E. Grin (eds.). 2010. Lakes on Mars. Elsevier. NY</ref> What appear to be plates of broken ice, ranging in size from 30&nbsp;m to 30&nbsp;km, are found in channels leading to a flooded area of approximately the same depth and width as the [[North Sea]]. The plates show signs of break up and rotation that clearly distinguish them from lava plates elsewhere on the surface of Mars. The source for the flood is thought to be the nearby geological fault [[Cerberus Fossae]] which spewed water as well as lava aged some 2 to 10 million years. It was suggested that the water exited the [[Cerberus Fossae]] then pooled and froze in the low, level plains and that such lakes may still exist.<ref name="Murray2007">{{cite journal|last=Murray |first=John B. |author2=''et al.'' |year=2005 |title=Evidence from the Mars Express High Resolution Stereo Camera for a frozen sea close to Mars' equator |journal=Nature |pmid=15772653 |volume=434 |issue= 7031|pages=352–356 |doi=10.1038/nature03379 |url=http://www.nature.com/nature/journal/v434/n7031/abs/nature03379.html |quote= Here we present High Resolution Stereo Camera images from the European Space Agency Mars Express spacecraft that indicate that such lakes may still exist. |bibcode = 2005Natur.434..352M }}</ref> Not all scientists agree with these conclusions.<ref name="Carr" /><ref>{{cite journal | last1=Orosei | first1=R. | last2=Cartacci | first2=M. | last3=Cicchetti | first3=A. | last4=Noschese | first4=R. | last5=Federico | first5=C. | last6=Frigeri | first6=A. | last7=Flamini | first7=E. | last8=Holt | first8=J. W. | last9=Marinangeli | first9=L. | title=Radar subsurface sounding over the putative frozen sea in Cerberus Palus, Mars | url=http://www.lpi.usra.edu/meetings/lpsc2008/pdf/1866.pdf | format=PDF | bibcode = 2007AGUFM.P14B..05O | doi = 10.1109/ICGPR.2010.5550143 |volume= XXXIX | journal=Lunar and Planetary Science | page=1 |year=2008 | isbn=978-1-4244-4604-9}}</ref><ref>ISBN 978-0-521-85226-5</ref>


=== Polar ice caps ===
=== Polar ice caps ===
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[[File:Conical mound in trough on Mars' north pole.jpg|thumb|North polar layered deposits of ice and dust]]
[[File:Conical mound in trough on Mars' north pole.jpg|thumb|North polar layered deposits of ice and dust]]


Mars has experienced large scale changes in the amount and distribution of ice on its surface in its relatively recent geological past, and as on Earth, these are known as ice ages. However, ice ages on Mars are very different from the ones that the Earth experiences. During a Martian ice age, the poles get warmer, and water ice then leaves the ice caps and is redeposited in mid latitudes.<ref name="IceAge&shy;" /> The moisture from the ice caps travels to lower latitudes in the form of deposits of frost or snow mixed with dust. The atmosphere of Mars contains a great deal of fine dust particles, the water vapor condenses on these particles which then fall down to the ground due to the additional weight of the water coating. When ice at the top of the mantling layer returns to the atmosphere, it leaves behind dust which serves to insulate the remaining ice.<ref name="IceAge&shy;" /> The total volume of water removed is a few percent of the ice caps, or enough to cover the entire surface of the planet under one meter of water. Much of this moisture from the ice caps results in a thick smooth mantle with a mixture of ice and dust.<ref name="Head, J. 2003" /><ref>{{cite journal|author=Mustard, J. ''et al.'' |year=2001 |title=Evidence for recent climate change on Mars from the identification of youthful near-surface ground ice |journal=Nature |volume=412 |pages=411–4 |pmid=11473309 |issue=6845 |doi=10.1038/35086515}}</ref><ref>{{cite journal|author=Kreslavsky, M.; J. Head |year=2002 |title=Mars: Nature and evolution of young latitude-dependent water-ice-rich mantle|issue=15 |journal=Geophysical Research Letters |volume=29 |url=http://www.planetary.brown.edu/pdfs/2756.pdf | format=PDF | doi = 10.1029/2002GL015392 |bibcode=2002GeoRL..29o..14K}}</ref> This ice-rich mantle, a few meters thick, smoothes the land at lower latitudes, but in places it displays a bumpy texture. Multiple stages of glaciations probably occurred.<ref name='Pavonis Mons'>{{cite journal | last1 = Shean | first1 = David E. | title = Origin and evolution of a cold-based tropical mountain glacier on Mars: The Pavonis Mons fan-shaped deposit | journal=Journal of Geophysical Research | volume = 110 | year = 2005 | doi = 10.1029/2004JE002360 | bibcode=2005JGRE..11005001S}}</ref> Because there are few craters on the current mantle, it is thought to be relatively young. It is thought that this mantle was laid in place during a relatively recent ice age.
Mars has experienced large scale changes in the amount and distribution of ice on its surface in its relatively recent geological past, and as on Earth, these are known as ice ages. However, ice ages on Mars are very different from the ones that the Earth experiences. During a Martian ice age, the poles get warmer, and water ice then leaves the ice caps and is redeposited in mid latitudes.<ref name="IceAge­" /> The moisture from the ice caps travels to lower latitudes in the form of deposits of frost or snow mixed with dust. The atmosphere of Mars contains a great deal of fine dust particles, the water vapor condenses on these particles which then fall down to the ground due to the additional weight of the water coating. When ice at the top of the mantling layer returns to the atmosphere, it leaves behind dust which serves to insulate the remaining ice.<ref name="IceAge­" /> The total volume of water removed is a few percent of the ice caps, or enough to cover the entire surface of the planet under one meter of water. Much of this moisture from the ice caps results in a thick smooth mantle with a mixture of ice and dust.<ref name="Head, J. 2003" /><ref>{{cite journal|author=Mustard, J. ''et al.'' |year=2001 |title=Evidence for recent climate change on Mars from the identification of youthful near-surface ground ice |journal=Nature |volume=412 |pages=411–4 |pmid=11473309 |issue=6845 |doi=10.1038/35086515}}</ref><ref>{{cite journal|author=Kreslavsky, M.; J. Head |year=2002 |title=Mars: Nature and evolution of young latitude-dependent water-ice-rich mantle|issue=15 |journal=Geophysical Research Letters |volume=29 |url=http://www.planetary.brown.edu/pdfs/2756.pdf | format=PDF | doi = 10.1029/2002GL015392 |bibcode=2002GeoRL..29o..14K}}</ref> This ice-rich mantle, a few meters thick, smoothes the land at lower latitudes, but in places it displays a bumpy texture. Multiple stages of glaciations probably occurred.<ref name='Pavonis Mons'>{{cite journal | last1 = Shean | first1 = David E. | title = Origin and evolution of a cold-based tropical mountain glacier on Mars: The Pavonis Mons fan-shaped deposit | journal=Journal of Geophysical Research | volume = 110 | year = 2005 | doi = 10.1029/2004JE002360 | bibcode=2005JGRE..11005001S}}</ref> Because there are few craters on the current mantle, it is thought to be relatively young. It is thought that this mantle was laid in place during a relatively recent ice age.


Ice ages are driven by changes in Mars's orbit and tilt, which can be compared to terrestrial [[Milankovich cycles]]. However, orbital calculations show that Mars wobbles on its axis far more than Earth does. The Earth is stabilized by its proportionally large moon, so it only wobbles a few degrees. Mars, in contrast, may change its tilt—also known as its [[obliquity]]—by many tens of degrees.<ref name=hirise /> When this obliquity is high, its poles get much more direct sunlight and heat; this causes the ice caps to warm and become smaller as ice sublimes. Adding to the variability of the climate, the [[Orbital eccentricity|eccentricity]] of the orbit of Mars changes twice as much as Earth's eccentricity. As the poles sublime, the ice is redeposited closer to the equator, which receive somewhat less [[solar insolation]] at these high obliquities. Computer simulations have shown that a 45° tilt of the Martian axis would result in ice accumulation in areas that display glacial landforms.<ref>{{cite journal|author=Forget, F. ''et al.'' |year=2006 |title=Formation of Glaciers on Mars by Atmospheric Precipitation at High Obliquity |journal=Science |volume=311 |pages=368–71 |pmid=16424337 |issue=5759 |doi=10.1126/science.1120335|bibcode = 2006Sci...311..368F }}</ref> A 2008 study provided evidence for multiple glacial phases during Late [[Amazonian (Mars)|Amazonian]] glaciation at the [[Martian dichotomy|dichotomy]] boundary on Mars.<ref name="Dickson2008">{{cite journal|last=Dickson |first=James L. |authorlink= |author2=Head, James W.|author3= Marchant, David R. |year=2008 |month= |title=Late Amazonian glaciation at the dichotomy boundary on Mars: Evidence for glacial thickness maxima and multiple glacial phases|journal=[[Geology (journal)|Geology]] |volume=36 |issue=5 |pages=411–4 |doi=10.1130/G24382A.1 }}</ref>
Ice ages are driven by changes in Mars's orbit and tilt, which can be compared to terrestrial [[Milankovich cycles]]. However, orbital calculations show that Mars wobbles on its axis far more than Earth does. The Earth is stabilized by its proportionally large moon, so it only wobbles a few degrees. Mars, in contrast, may change its tilt—also known as its [[obliquity]]—by many tens of degrees.<ref name=hirise /> When this obliquity is high, its poles get much more direct sunlight and heat; this causes the ice caps to warm and become smaller as ice sublimes. Adding to the variability of the climate, the [[Orbital eccentricity|eccentricity]] of the orbit of Mars changes twice as much as Earth's eccentricity. As the poles sublime, the ice is redeposited closer to the equator, which receive somewhat less [[solar insolation]] at these high obliquities. Computer simulations have shown that a 45° tilt of the Martian axis would result in ice accumulation in areas that display glacial landforms.<ref>{{cite journal|author=Forget, F. ''et al.'' |year=2006 |title=Formation of Glaciers on Mars by Atmospheric Precipitation at High Obliquity |journal=Science |volume=311 |pages=368–71 |pmid=16424337 |issue=5759 |doi=10.1126/science.1120335|bibcode = 2006Sci...311..368F }}</ref> A 2008 study provided evidence for multiple glacial phases during Late [[Amazonian (Mars)|Amazonian]] glaciation at the [[Martian dichotomy|dichotomy]] boundary on Mars.<ref name="Dickson2008">{{cite journal|last=Dickson |first=James L. |authorlink= |author2=Head, James W.|author3= Marchant, David R. |date= 2008 |title=Late Amazonian glaciation at the dichotomy boundary on Mars: Evidence for glacial thickness maxima and multiple glacial phases|journal=[[Geology (journal)|Geology]] |volume=36 |issue=5 |pages=411–4 |doi=10.1130/G24382A.1 }}</ref>


== Evidence for recent flows ==
== Evidence for recent flows ==
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[[File:Branched gullies.jpg|thumb|Branched gullies]]
[[File:Branched gullies.jpg|thumb|Branched gullies]]
[[File:Deep Gullies.jpg|thumb|Group of deep gullies]]
[[File:Deep Gullies.jpg|thumb|Group of deep gullies]]
Liquid water cannot exist in a stable form on the surface of Mars with its present low atmospheric pressure and low temperature, except at the lowest elevations for a few hours.<ref name=Kostama /><ref name=flows /> So, a geological mystery commenced when observations from NASA's ''[[Mars Reconnaissance Orbiter]]'' revealed [[Gully (Mars)|gully]] deposits that were not there ten years ago, possibly caused by flowing salty water ([[brine]]) during the warmest months on Mars.<ref>{{cite web|url=http://www.sciencedaily.com/releases/2009/02/090213110731.htm |title=Mars Gullies May Have Been Formed By Flowing Liquid Brine |publisher=Sciencedaily.com |date=2009-02-15 |accessdate=2013-02-10}}</ref><ref name=voanews>{{cite web| url= http://www.voanews.com/english/news/science-technology/NASA-Finds-Possible-Signs-of-Flowing-Water-on-Mars-126807133.html| title=NASA Finds Possible Signs of Flowing Water on Mars| publisher=voanews.com| accessdate=August 5, 2011}}</ref><ref>{{cite web|author=Jpl.Nasa.Gov |url= http://www.jpl.nasa.gov/news/news.cfm?release=2006-145 |title=JPL news release 2006-145 | publisher=Jpl.nasa.gov |date=2006-12-06 |accessdate=2012-01-16}}</ref><ref name='Impact Cratering Rate'>{{cite journal| title=Present-Day Impact Cratering Rate and Contemporary Gully Activity on Mars| journal=Science| date=8 December 2006|first=Michael C.|last=Malin| coauthors=Kenneth S. Edgett, Liliya V. Posiolova, Shawn M. McColley, Eldar Z. Noe Dobrea| volume=314| issue=5805| pages=1573–1577| doi=10.1126/science.1135156| url=http://www.sciencemag.org/cgi/content/abstract/314/5805/1573 |format= |accessdate=2009-09-03| pmid=17158321 |bibcode = 2006Sci...314.1573M }}</ref><ref name="Malin, M 2001">{{cite journal | last1=Malin | first1=Michael C. | last2=Edgett | first2=Kenneth S. | title=Mars Global Surveyor Mars Orbiter Camera: Interplanetary cruise through primary mission | pages=23429–23570 |journal=Journal of Geophysical Research | year=2001 | doi = 10.1029/2000JE001455 | volume=106 | bibcode=2001JGR...10623429M}}</ref><ref name='Impact Cratering Rate' /><ref>{{cite web|url=http://www.msss.com/mars_images/moc/2006/12/06/gullies/sirenum_crater/index.html |title=Mars Global Surveyor MOC2-1618 Release |doi=10.1126/science.288.5475.2330 |publisher=Msss.com |accessdate=December 19, 2010}}</ref><ref>{{cite web|url=http://www.space.com/scienceastronomy/061206_mars_gullies.html |title=Changing Mars Gullies Hint at Recent Flowing Water |publisher=SPACE.com |date=December 6, 2006 |accessdate=December 19, 2010}}</ref><ref>{{cite web| url=http://mars.jpl.nasa.gov/mgs/msss/camera/images/june2000/ab1/index.html |title=Mars Global Surveyor MOC2-239 Release |publisher=Mars.jpl.nasa.gov |accessdate=December 19, 2010}}</ref><ref name="Head 2008 PNAS">{{cite journal | pmid=18725636 | year=2008 | last1=Head | first1=JW | last2=Marchant | first2=DR | last3=Kreslavsky | first3=MA | title=Formation of gullies on Mars: Link to recent climate history and insolation microenvironments implicate surface water flow origin | volume=105 | issue=36 | pages=13258–63 | doi=10.1073/pnas.0803760105 | pmc=2734344 | journal=[[Proceedings of the National Academy of Sciences of the United States of America|PNAS]] | bibcode=2008PNAS..10513258H }}</ref> The images were of two craters called [[Terra Sirenum]] and [[Centauri Montes]] which appear to show the presence of liquid water flows on Mars at some point between 1999 and 2001.<ref name='Impact Cratering Rate' /><ref>{{cite news | url=http://www.timesonline.co.uk/article/0,,3-2491082,00.html |title=Water has been flowing on Mars within past five years, Nasa says |work=The Times |location=UK |accessdate=March 17, 2007 |first=Mark |last=Henderson |date=December 7, 2006}}</ref><ref>[http://www.csmonitor.com/2006/1207/p01s02-usgn.html Mars photo evidence shows recently running water.] ''The Christian Science Monitor''. Retrieved on March 17, 2007</ref><ref>{{cite journal|last=Malin|first=Michael C.|author2=Edgett, Kenneth S.|year=2000|title=Evidence for Recent Groundwater Seepage and Surface Runoff on Mars| journal=Science| volume=288| issue=5475| pages=2330–2335| doi=10.1126/science.288.5475.2330|url=|accessdate=|quote=|pmid=10875910 |bibcode = 2000Sci...288.2330M }}</ref>
Liquid water cannot exist in a stable form on the surface of Mars with its present low atmospheric pressure and low temperature, except at the lowest elevations for a few hours.<ref name=Kostama /><ref name=flows /> So, a geological mystery commenced when observations from NASA's ''[[Mars Reconnaissance Orbiter]]'' revealed [[Gully (Mars)|gully]] deposits that were not there ten years ago, possibly caused by flowing salty water ([[brine]]) during the warmest months on Mars.<ref>{{cite web|url=http://www.sciencedaily.com/releases/2009/02/090213110731.htm |title=Mars Gullies May Have Been Formed By Flowing Liquid Brine |publisher=Sciencedaily.com |date=2009-02-15 |accessdate=2013-02-10}}</ref><ref name=voanews>{{cite web| url= http://www.voanews.com/english/news/science-technology/NASA-Finds-Possible-Signs-of-Flowing-Water-on-Mars-126807133.html| title=NASA Finds Possible Signs of Flowing Water on Mars| publisher=voanews.com| accessdate=August 5, 2011}}</ref><ref>{{cite web|author=Jpl.Nasa.Gov |url= http://www.jpl.nasa.gov/news/news.cfm?release=2006-145 |title=JPL news release 2006-145 | publisher=Jpl.nasa.gov |date=2006-12-06 |accessdate=2012-01-16}}</ref><ref name='Impact Cratering Rate'>{{cite journal| title=Present-Day Impact Cratering Rate and Contemporary Gully Activity on Mars| journal=Science| date=8 December 2006|first=Michael C.|last=Malin|first2=Kenneth S.|last2=Edgett|first3=Liliya V.|last3=Posiolova|first4=Shawn M.|last4=McColley|first5=Eldar Z. Noe|last5=Dobrea| volume=314| issue=5805| pages=1573–1577| doi=10.1126/science.1135156| url=http://www.sciencemag.org/cgi/content/abstract/314/5805/1573 |format= |accessdate=2009-09-03| pmid=17158321 |bibcode = 2006Sci...314.1573M }}</ref><ref name="Malin, M 2001">{{cite journal | last1=Malin | first1=Michael C. | last2=Edgett | first2=Kenneth S. | title=Mars Global Surveyor Mars Orbiter Camera: Interplanetary cruise through primary mission | pages=23429–23570 |journal=Journal of Geophysical Research | year=2001 | doi = 10.1029/2000JE001455 | volume=106 | bibcode=2001JGR...10623429M}}</ref><ref name='Impact Cratering Rate' /><ref>{{cite web|url=http://www.msss.com/mars_images/moc/2006/12/06/gullies/sirenum_crater/index.html |title=Mars Global Surveyor MOC2-1618 Release |doi=10.1126/science.288.5475.2330 |publisher=Msss.com |accessdate=December 19, 2010}}</ref><ref>{{cite web|url=http://www.space.com/scienceastronomy/061206_mars_gullies.html |title=Changing Mars Gullies Hint at Recent Flowing Water |publisher=SPACE.com |date=December 6, 2006 |accessdate=December 19, 2010}}</ref><ref>{{cite web| url=http://mars.jpl.nasa.gov/mgs/msss/camera/images/june2000/ab1/index.html |title=Mars Global Surveyor MOC2-239 Release |publisher=Mars.jpl.nasa.gov |accessdate=December 19, 2010}}</ref><ref name="Head 2008 PNAS">{{cite journal | pmid=18725636 | year=2008 | last1=Head | first1=JW | last2=Marchant | first2=DR | last3=Kreslavsky | first3=MA | title=Formation of gullies on Mars: Link to recent climate history and insolation microenvironments implicate surface water flow origin | volume=105 | issue=36 | pages=13258–63 | doi=10.1073/pnas.0803760105 | pmc=2734344 | journal=[[Proceedings of the National Academy of Sciences of the United States of America|PNAS]] | bibcode=2008PNAS..10513258H }}</ref> The images were of two craters called [[Terra Sirenum]] and [[Centauri Montes]] which appear to show the presence of liquid water flows on Mars at some point between 1999 and 2001.<ref name='Impact Cratering Rate' /><ref>{{cite news | url=http://www.timesonline.co.uk/article/0,,3-2491082,00.html |title=Water has been flowing on Mars within past five years, Nasa says |work=The Times |location=UK |accessdate=March 17, 2007 |first=Mark |last=Henderson |date=December 7, 2006}}</ref><ref>[http://www.csmonitor.com/2006/1207/p01s02-usgn.html Mars photo evidence shows recently running water.] ''The Christian Science Monitor''. Retrieved on March 17, 2007</ref><ref>{{cite journal|last=Malin|first=Michael C.|author2=Edgett, Kenneth S.|year=2000|title=Evidence for Recent Groundwater Seepage and Surface Runoff on Mars| journal=Science| volume=288| issue=5475| pages=2330–2335| doi=10.1126/science.288.5475.2330|url=|accessdate=|quote=|pmid=10875910 |bibcode = 2000Sci...288.2330M }}</ref>


There is disagreement in the scientific community as to whether or not gullies are formed by liquid water. It is also possible that the flows that carve gullies are dry,<ref>{{cite journal | doi = 10.1016/j.icarus.2009.09.009 | last1 = Kolb | first1 = K. | last2 = Pelletier | year = 2010 | first2 = Jon D. | last3 = McEwen | first3 = Alfred S. | title = Modeling the formation of bright slope deposits associated with gullies in Hale Crater, Mars: Implications for recent liquid water | url = | journal=Icarus | volume = 205 | pages = 113–137 |bibcode = 2010Icar..205..113K }}</ref> or perhaps lubricated by carbon dioxide.<ref>Hoffman, Nick. "Active polar gullies on Mars and the role of carbon dioxide." Astrobiology 2.3 (2002) 313-323.</ref><ref>Musselwhite, Donald S., Timothy D. Swindle, and Jonathan I. Lunine. "Liquid CO2 breakout and the formation of recent small gullies on Mars." Geophysical research letters 28.7 (2001) 1283–1285.</ref> Even if gullies are carved by flowing water at the surface, the exact source of the water and the mechanisms behind its motion are not well understood.<ref name=hirise2>{{cite journal |last1=McEwen| first1=Alfred.S.| last2=Ojha| first2=Lujendra| last3=Dundas|first3=Colin M.|date=June 17, 2011|title=Seasonal Flows on Warm Martian Slopes| journal=Science| volume=333| issue=6043| pages=740–743| publisher=American Association for the Advancement of Science| doi=10.1126/science.1204816| issn=0036-8075| url=http://www.sciencemag.org/content/333/6043/740| accessdate=August 5, 2011| bibcode = 2011Sci...333..740M| pmid=21817049}}</ref>
There is disagreement in the scientific community as to whether or not gullies are formed by liquid water. It is also possible that the flows that carve gullies are dry,<ref>{{cite journal | doi = 10.1016/j.icarus.2009.09.009 | last1 = Kolb | first1 = K. | last2 = Pelletier | year = 2010 | first2 = Jon D. | last3 = McEwen | first3 = Alfred S. | title = Modeling the formation of bright slope deposits associated with gullies in Hale Crater, Mars: Implications for recent liquid water | url = | journal=Icarus | volume = 205 | pages = 113–137 |bibcode = 2010Icar..205..113K }}</ref> or perhaps lubricated by carbon dioxide.<ref>Hoffman, Nick. "Active polar gullies on Mars and the role of carbon dioxide." Astrobiology 2.3 (2002) 313-323.</ref><ref>Musselwhite, Donald S., Timothy D. Swindle, and Jonathan I. Lunine. "Liquid CO2 breakout and the formation of recent small gullies on Mars." Geophysical research letters 28.7 (2001) 1283–1285.</ref> Even if gullies are carved by flowing water at the surface, the exact source of the water and the mechanisms behind its motion are not well understood.<ref name=hirise2>{{cite journal |last1=McEwen| first1=Alfred.S.| last2=Ojha| first2=Lujendra| last3=Dundas|first3=Colin M.|date=June 17, 2011|title=Seasonal Flows on Warm Martian Slopes| journal=Science| volume=333| issue=6043| pages=740–743| publisher=American Association for the Advancement of Science| doi=10.1126/science.1204816| issn=0036-8075| url=http://www.sciencemag.org/content/333/6043/740| accessdate=August 5, 2011| bibcode = 2011Sci...333..740M| pmid=21817049}}</ref>
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{{Main|Life on Mars}}
{{Main|Life on Mars}}


Life is understood to [[Life and water|require liquid water]], but it is not the only essential requirement for life.<ref>{{cite web |url=http://cmapsnasacmex.ihmc.us/servlet/SBReadResourceServlet?rid=1025200161109_2045745605_1714&partName=htmltext |title=Essential requirements for life |accessdate=2013-05-26 |publisher=CMEX-NASA}}</ref><ref name='D.C.Golden'>{{cite journal | title = Biotoxicity of Marssoils:1. Dry deposition of analog soils on microbial colonies and survival under Martian conditions | journal = Elsevier -Planetary and Space Science | date = 20 July 2012 |last1=Schuerger |first1=Andrew C. |last2=Golden |first2=D.C. |last3=Ming |first3=Doug W. |url = http://plantpath.ifas.ufl.edu/faculty/statewide/schuerger/Schuerger_2012_PSS-3371.pdf | format = PDF | accessdate = 2013-06-06}}</ref><ref name=Beaty>{{citation | first = David W. | last = Beaty | coauthors = et al. | contribution = MEPAG SR-SAG (2006) Unpublished white paper | title = Findings of the Mars Special Regions Science Analysis Group | editor-first = the Mars Exploration Program Analysis Group (MEPAG) | publisher = Jet Propulsion Laboratory – NASA | pages = 17 | date = July 14, 2006 | contribution-url = http://mepag.jpl.nasa.gov/reports/MEPAG_SR-SAG_final1.pdf | format = PDF | accessdate = 2013-06-06}}</ref> These requirements include water, an energy source, and materials necessary for cellular growth, while all under appropriate environmental conditions.<ref>[http://adsabs.harvard.edu/abs/2012DPS....4421522F Technologies for the Discovery and Characterization of Subsurface Habitable Environments on Mars]</ref> The confirmation that liquid water once flowed on Mars, the existence of nutrients, and the previous discovery of a past [[magnetosphere|magnetic field]] that protected the planet from [[cosmic radiation|cosmic]] and [[solar radiation]],<ref>{{cite web | url=http://www.nasa.gov/centers/goddard/news/topstory/2005/mgs_plates.html | title=New Map Provides More Evidence Mars Once Like Earth | publisher=NASA | work=Goddard Space Flight Center | date=October 12, 2005 | accessdate=5 June 2013 | author= Neal-Jones, Nancy | coauthor =O'Carroll, Cynthia}}</ref><ref>{{cite web| title=Martian Interior: Paleomagnetism |publisher=European Space Agency |work=Mars Express |date=4 January 2007 |url=http://sci.esa.int/science-e/www/object/index.cfm?fobjectid=31028&fbodylongid=645}}</ref> together strongly suggest that Mars could have had the environmental factors to support life.<ref name='Wall' /> To be clear, the find of past habitability is not evidence that Martian life has ever actually existed.
Life is understood to [[Life and water|require liquid water]], but it is not the only essential requirement for life.<ref>{{cite web |url=http://cmapsnasacmex.ihmc.us/servlet/SBReadResourceServlet?rid=1025200161109_2045745605_1714&partName=htmltext |title=Essential requirements for life |accessdate=2013-05-26 |publisher=CMEX-NASA}}</ref><ref name='D.C.Golden'>{{cite journal | title = Biotoxicity of Marssoils:1. Dry deposition of analog soils on microbial colonies and survival under Martian conditions | journal = Elsevier -Planetary and Space Science | date = 20 July 2012 |last1=Schuerger |first1=Andrew C. |last2=Golden |first2=D.C. |last3=Ming |first3=Doug W. |url = http://plantpath.ifas.ufl.edu/faculty/statewide/schuerger/Schuerger_2012_PSS-3371.pdf | format = PDF | accessdate = 2013-06-06}}</ref><ref name=Beaty>{{citation | first = David W. | last = Beaty | author2 = et al. | contribution = MEPAG SR-SAG (2006) Unpublished white paper | title = Findings of the Mars Special Regions Science Analysis Group | editor-first = the Mars Exploration Program Analysis Group (MEPAG) | publisher = Jet Propulsion Laboratory – NASA | pages = 17 | date = July 14, 2006 | contribution-url = http://mepag.jpl.nasa.gov/reports/MEPAG_SR-SAG_final1.pdf | format = PDF | accessdate = 2013-06-06}}</ref> These requirements include water, an energy source, and materials necessary for cellular growth, while all under appropriate environmental conditions.<ref>[http://adsabs.harvard.edu/abs/2012DPS....4421522F Technologies for the Discovery and Characterization of Subsurface Habitable Environments on Mars]</ref> The confirmation that liquid water once flowed on Mars, the existence of nutrients, and the previous discovery of a past [[magnetosphere|magnetic field]] that protected the planet from [[cosmic radiation|cosmic]] and [[solar radiation]],<ref>{{cite web | url=http://www.nasa.gov/centers/goddard/news/topstory/2005/mgs_plates.html | title=New Map Provides More Evidence Mars Once Like Earth | publisher=NASA | work=Goddard Space Flight Center | date=October 12, 2005 | accessdate=5 June 2013 | author= Neal-Jones, Nancy |last2=O'Carroll|first2= Cynthia}}</ref><ref>{{cite web| title=Martian Interior: Paleomagnetism |publisher=European Space Agency |work=Mars Express |date=4 January 2007 |url=http://sci.esa.int/science-e/www/object/index.cfm?fobjectid=31028&fbodylongid=645}}</ref> together strongly suggest that Mars could have had the environmental factors to support life.<ref name='Wall' /> To be clear, the find of past habitability is not evidence that Martian life has ever actually existed.
[[File:ALH84001 structures.jpg|thumb|left|An electron microscope reveals bacteria-like structures in meteorite fragment [[ALH84001]]]]
[[File:ALH84001 structures.jpg|thumb|left|An electron microscope reveals bacteria-like structures in meteorite fragment [[ALH84001]]]]
When there is a [[magnetosphere|magnetic field]], the atmosphere is protected from erosion by [[solar wind]], and ensures the maintenance of a dense atmosphere, necessary for liquid water to exist on the surface of Mars.<ref name='Dehant'>{{cite journal | title = Planetary Magnetic Dynamo Effect on Atmospheric Protection of Early Earth and Mars | journal = Space Sciences Series of ISSI | year = 2007 | first = V. Dehant | coauthors = H. Lammer, Y. N. Kulikov, J. -M. Grießmeier, et al. | volume = 24 | pages = 279–300 | url = http://link.springer.com/chapter/10.1007/978-0-387-74288-5_10 | accessdate = 2013-06-06}}</ref><ref name='hostile to life'>{{cite news | title = What makes Mars so hostile to life? | date = 7 January 2013 | url = http://www.bbc.co.uk/science/0/20915340 | work = BBC News | accessdate = 2013-06-15}}</ref> The two current ecological approaches for predicting the potential habitability of the Martian surface use 19 or 20 environmental factors, with emphasis on water availability, temperature, presence of nutrients, an energy source, and protection from solar ultraviolet and [[Cosmic ray|galactic cosmic
When there is a [[magnetosphere|magnetic field]], the atmosphere is protected from erosion by [[solar wind]], and ensures the maintenance of a dense atmosphere, necessary for liquid water to exist on the surface of Mars.<ref name='Dehant'>{{cite journal | title = Planetary Magnetic Dynamo Effect on Atmospheric Protection of Early Earth and Mars | journal = Space Sciences Series of ISSI | year = 2007 | first = V.|last= Dehant |first2=H.|last2=Lammer|first3=Y. N.|last3=Kulikov|first4=J. -M.|last4=Grießmeier|first5=et|last5=al.| volume = 24 | pages = 279–300 | url = http://link.springer.com/chapter/10.1007/978-0-387-74288-5_10 | accessdate = 2013-06-06}}</ref><ref name='hostile to life'>{{cite news | title = What makes Mars so hostile to life? | date = 7 January 2013 | url = http://www.bbc.co.uk/science/0/20915340 | work = BBC News | accessdate = 2013-06-15}}</ref> The two current ecological approaches for predicting the potential habitability of the Martian surface use 19 or 20 environmental factors, with emphasis on water availability, temperature, presence of nutrients, an energy source, and protection from solar ultraviolet and [[Cosmic ray|galactic cosmic
radiation]].<ref name='D.C.Golden' /><ref name=Beaty /> In particular, the damaging effect of ionising radiation on cellular structure is one of the prime limiting factors on the survival of life in potential astrobiological habitats.<ref name='Dartnell-1' /><ref name='ionising radiation' /> Even at a depth of 2 meters beneath the surface, any microbes would likely be dormant, cryopreserved by the current freezing conditions, and so metabolically inactive and unable to repair cellular degradation as it occurs.<ref name='Dartnell-1' /><ref name='ionising radiation' /><ref name='Parnell'>{{cite news | first = JohnThomas Didymus | title = Scientists find evidence Mars subsurface could hold life | date = 21 January | url = http://digitaljournal.com/article/341801 | work = Digital Journal – Science | accessdate = 2013-06-05 | quote = There can be no life on the surface of Mars because it is bathed in radiation and it's completely frozen. However, life in the subsurface would be protected from that. - Prof. Parnell.}}</ref><ref name=Beaty /><ref name='cosmic radiation'>{{cite web | url = http://www.space.com/3396-study-surface-mars-devoid-life.html | title = Study: Surface of Mars Devoid of Life | accessdate = 28 May 2013 | first = Ker Than | date = 29 January 2007 | work = Space.com| quote = After mapping cosmic radiation levels at various depths on Mars, researchers have concluded that any life within the first several yards of the planet's surface would be killed by lethal doses of cosmic radiation.}}</ref><ref name='Dartnell'>{{cite journal | title = Modelling the surface and subsurface Martian radiation environment: Implications for astrobiology | journal = Geophysical Research Letters | date = 30 January 2007 | first = L.R. | last = Dartnell | coauthors = Desorgher, Ward, Coates | volume = 34 | issue = 2 | doi = 10.1029/2006GL027494 | url = http://onlinelibrary.wiley.com/doi/10.1029/2006GL027494/abstract | accessdate = 2013-05-26 | quote = Bacteria or spores held dormant by freezing conditions cannot metabolise and become inactivated by accumulating radiation damage. We find that at 2&nbsp;m depth, the reach of the ExoMars drill, a population of radioresistant cells would need to have reanimated within the last 450,000 years to still be viable. Recovery of viable cells cryopreserved within the putative Cerberus pack-ice requires a drill depth of at least 7.5 m.|bibcode = 2007GeoRL..34.2207D }}</ref><ref name='DartnellGeographic'>{{cite web | author = Richard A. Lovet | title = Mars Life May Be Too Deep to Find, Experts Conclude| url = http://news.nationalgeographic.co.uk/news/2007/02/070202-mars-life.html | work = National Geographic News |date= February 2, 2007 |quote=That's because any bacteria that may once have lived on the surface have long since been exterminated by cosmic radiation sleeting through the thin Martian atmosphere.}}</ref>
radiation]].<ref name='D.C.Golden' /><ref name=Beaty /> In particular, the damaging effect of ionising radiation on cellular structure is one of the prime limiting factors on the survival of life in potential astrobiological habitats.<ref name='Dartnell-1' /><ref name='ionising radiation' /> Even at a depth of 2 meters beneath the surface, any microbes would likely be dormant, cryopreserved by the current freezing conditions, and so metabolically inactive and unable to repair cellular degradation as it occurs.<ref name='Dartnell-1' /><ref name='ionising radiation' /><ref name='Parnell'>{{cite news | first = JohnThomas Didymus | title = Scientists find evidence Mars subsurface could hold life | date = 21 January | url = http://digitaljournal.com/article/341801 | work = Digital Journal – Science | accessdate = 2013-06-05 | quote = There can be no life on the surface of Mars because it is bathed in radiation and it's completely frozen. However, life in the subsurface would be protected from that. - Prof. Parnell.}}</ref><ref name=Beaty /><ref name='cosmic radiation'>{{cite web | url = http://www.space.com/3396-study-surface-mars-devoid-life.html | title = Study: Surface of Mars Devoid of Life | accessdate = 28 May 2013 | first = Ker Than | date = 29 January 2007 | work = Space.com| quote = After mapping cosmic radiation levels at various depths on Mars, researchers have concluded that any life within the first several yards of the planet's surface would be killed by lethal doses of cosmic radiation.}}</ref><ref name='Dartnell'>{{cite journal | title = Modelling the surface and subsurface Martian radiation environment: Implications for astrobiology | journal = Geophysical Research Letters | date = 30 January 2007 | first = L.R. | last = Dartnell |author2=Desorgher|author3=Ward|author4=Coates| volume = 34 | issue = 2 | doi = 10.1029/2006GL027494 | url = http://onlinelibrary.wiley.com/doi/10.1029/2006GL027494/abstract | accessdate = 2013-05-26 | quote = Bacteria or spores held dormant by freezing conditions cannot metabolise and become inactivated by accumulating radiation damage. We find that at 2&nbsp;m depth, the reach of the ExoMars drill, a population of radioresistant cells would need to have reanimated within the last 450,000 years to still be viable. Recovery of viable cells cryopreserved within the putative Cerberus pack-ice requires a drill depth of at least 7.5 m.|bibcode = 2007GeoRL..34.2207D }}</ref><ref name='DartnellGeographic'>{{cite web | author = Richard A. Lovet | title = Mars Life May Be Too Deep to Find, Experts Conclude| url = http://news.nationalgeographic.co.uk/news/2007/02/070202-mars-life.html | work = National Geographic News |date= February 2, 2007 |quote=That's because any bacteria that may once have lived on the surface have long since been exterminated by cosmic radiation sleeting through the thin Martian atmosphere.}}</ref>


Therefore, the best potential locations for discovering [[life on Mars]] may be at subsurface environments that have not been studied yet.<ref name='Parnell' /><ref name=Steigerwald /><ref>[http://marsrovers.jpl.nasa.gov/newsroom/pressreleases/20080215a.html NASA – Mars Rovers Sharpen Questions About Livable Conditions]</ref><ref>{{cite news | title = Mars: 'Strongest evidence' planet may have supported life, scientists say | date = 20 January 2013 | url = http://www.bbc.co.uk/news/uk-scotland-north-east-orkney-shetland-21063817 | work = BBC News | accessdate = 2013-01-22}}</ref><ref>{{cite journal | title = Groundwater activity on Mars and implications for a deep biosphere | journal = Nature Geoscience | date = 20 January 2013 | first = Joseph R. Michalski | coauthors = Javier Cuadros, Paul B. Niles, John Parnell, A. Deanne Rogers, Shawn P. Wright | doi = 10.1038/ngeo1706 | url = http://www.nature.com/ngeo/journal/vaop/ncurrent/full/ngeo1706.html | accessdate = 2013-01-22|bibcode = 2013NatGe...6..133M }}</ref> The extensive [[Volcanology of Mars|volcanism]] in the past, possibly created subsurface cracks and caves within different strata, and liquid water could have been stored in these subterraneous places, forming large [[aquifer]]s with deposits of saline liquid water, minerals, organic molecules, and [[Geothermal gradient|geothermal heat]] – potentially providing a current habitable environment away from the harsh surface conditions.<ref name='subsurface habitability model' /><ref name='Parnell' /><ref name='Michalski' /><ref>{{cite news | first = Paul S. | last = Anderson | title = New Study Says Large Regions of Mars Could Sustain Life | date = 15 December 2011 | url = http://www.universetoday.com/91848/new-study-says-large-regions-of-mars-could-sustain-life/ | work = Universe Today | accessdate = 2013-06-05 | quote = Most scientists would agree that the best place that any organisms could hope to survive and flourish would be underground.}}</ref><ref>{{cite web|url= http://phoenix.lpl.arizona.edu/mars143.php | title = Habitability and Biology: What are the Properties of Life? | accessdate = 2013-06-06 | work = Phoenix Mars Mission | publisher = The University of Arizona | quote= If any life exists on Mars today, scientists believe it is most likely to be in pockets of liquid water beneath the Martian surface.}}</ref><ref>{{cite web | url = http://www.space.com/3632-mars-caves-targets-search-life.html | title = Possible New Mars Caves Targets in Search for Life | accessdate = 2013-06-15 | first = Ker Than, | date = 2 April 2007 | work = Space.com}}</ref><ref>{{citation | contribution = Thermodynamic Stability of Liquid Water on Present‐Day Mars: Surface | title = The Present-Day Habitability of Mars 2013 |last1=Hayne |first1=Paul O. |last2=Schofield |first2=John T. |last3=Kleinböhl |first3=Armin |last4=Kass |first4=David A. |last5=McCleese |first5=Daniel J. | publisher = The UCLA Institute for Planets and Exoplanets | place = California, USA | date = February 4–6, 2013 | contribution-url = http://planets.ucla.edu/wp-content/form-data/mars-abstracts-2013/73-hayne_marsconf_UCLA_2013.pdf | format = PDF | accessdate = 2013-06-17| quote= These results suggest that present day fluvial activity [gullies] on Mars may be associated with discharge from aquifers supplied during seasonal or inter‐annual climate cycles, rather than ubiquitous ground ice.}}</ref>
Therefore, the best potential locations for discovering [[life on Mars]] may be at subsurface environments that have not been studied yet.<ref name='Parnell' /><ref name=Steigerwald /><ref>[http://marsrovers.jpl.nasa.gov/newsroom/pressreleases/20080215a.html NASA – Mars Rovers Sharpen Questions About Livable Conditions]</ref><ref>{{cite news | title = Mars: 'Strongest evidence' planet may have supported life, scientists say | date = 20 January 2013 | url = http://www.bbc.co.uk/news/uk-scotland-north-east-orkney-shetland-21063817 | work = BBC News | accessdate = 2013-01-22}}</ref><ref>{{cite journal | title = Groundwater activity on Mars and implications for a deep biosphere | journal = Nature Geoscience | date = 20 January 2013 | first = Joseph R.|last= Michalski |first2=Javier|last2=Cuadros|first3=Paul B.|last3=Niles|first4=John|last4=Parnell|first5=A. Deanne|last5=Rogers|first6=Shawn P.|last6=Wright| doi = 10.1038/ngeo1706 | url = http://www.nature.com/ngeo/journal/vaop/ncurrent/full/ngeo1706.html | accessdate = 2013-01-22|bibcode = 2013NatGe...6..133M }}</ref> The extensive [[Volcanology of Mars|volcanism]] in the past, possibly created subsurface cracks and caves within different strata, and liquid water could have been stored in these subterraneous places, forming large [[aquifer]]s with deposits of saline liquid water, minerals, organic molecules, and [[Geothermal gradient|geothermal heat]] – potentially providing a current habitable environment away from the harsh surface conditions.<ref name='subsurface habitability model' /><ref name='Parnell' /><ref name='Michalski' /><ref>{{cite news | first = Paul S. | last = Anderson | title = New Study Says Large Regions of Mars Could Sustain Life | date = 15 December 2011 | url = http://www.universetoday.com/91848/new-study-says-large-regions-of-mars-could-sustain-life/ | work = Universe Today | accessdate = 2013-06-05 | quote = Most scientists would agree that the best place that any organisms could hope to survive and flourish would be underground.}}</ref><ref>{{cite web|url= http://phoenix.lpl.arizona.edu/mars143.php | title = Habitability and Biology: What are the Properties of Life? | accessdate = 2013-06-06 | work = Phoenix Mars Mission | publisher = The University of Arizona | quote= If any life exists on Mars today, scientists believe it is most likely to be in pockets of liquid water beneath the Martian surface.}}</ref><ref>{{cite web | url = http://www.space.com/3632-mars-caves-targets-search-life.html | title = Possible New Mars Caves Targets in Search for Life | accessdate = 2013-06-15 | first = Ker Than, | date = 2 April 2007 | work = Space.com}}</ref><ref>{{citation | contribution = Thermodynamic Stability of Liquid Water on Present‐Day Mars: Surface | title = The Present-Day Habitability of Mars 2013 |last1=Hayne |first1=Paul O. |last2=Schofield |first2=John T. |last3=Kleinböhl |first3=Armin |last4=Kass |first4=David A. |last5=McCleese |first5=Daniel J. | publisher = The UCLA Institute for Planets and Exoplanets | place = California, USA | date = February 4–6, 2013 | contribution-url = http://planets.ucla.edu/wp-content/form-data/mars-abstracts-2013/73-hayne_marsconf_UCLA_2013.pdf | format = PDF | accessdate = 2013-06-17| quote= These results suggest that present day fluvial activity [gullies] on Mars may be associated with discharge from aquifers supplied during seasonal or inter‐annual climate cycles, rather than ubiquitous ground ice.}}</ref>


== Findings by probes ==
== Findings by probes ==
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| accessdate=September 14, 2008
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| format= PDF
| format= PDF
| bibcode=2005JGRE..11005004H}} 'conditions such as now occur on Mars, outside of the temperature-pressure stability regime of liquid water' 'Liquid water is typically stable at the lowest elevations and at low latitudes on the planet because the atmospheric pressure is greater than the vapor pressure of water and surface temperatures in equatorial regions can reach 273 K (-53 °C) for parts of the day.</ref><ref name="Arvidson, R. 2008">{{cite journal | last1=Arvidson | first1=P. H. | year= 2008 | last2=Tamppari | first2=L. | last3=Arvidson | first3=R. E. | last4=Bass | first4=D. | last5=Blaney | first5=D. | last6=Boynton | first6=W. | last7=Carswell | first7=A. | last8=Catling | first8=D. | last9=Clark | first9=B. |title= Introduction to special section on the phoenix mission: Landing site characterization experiments, mission overviews, and expected science |journal=J. Geophysical Research |volume= 113 |doi = 10.1029/2008JE003083 | bibcode=2008JGRE..11300A18S}}</ref><ref name='Dirt find'>{{cite web|url=http://www.space.com/scienceastronomy/090702-phoenix-soil.html |title=The Dirt on Mars Lander Soil Findings |publisher=SPACE.com |accessdate=December 19, 2010}}</ref>
| bibcode=2005JGRE..11005004H}} 'conditions such as now occur on Mars, outside of the temperature-pressure stability regime of liquid water' ... 'Liquid water is typically stable at the lowest elevations and at low latitudes on the planet because the atmospheric pressure is greater than the vapor pressure of water and surface temperatures in equatorial regions can reach 273 K (-53 °C) for parts of the day.</ref><ref name="Arvidson, R. 2008">{{cite journal | last1=Arvidson | first1=P. H. | year= 2008 | last2=Tamppari | first2=L. | last3=Arvidson | first3=R. E. | last4=Bass | first4=D. | last5=Blaney | first5=D. | last6=Boynton | first6=W. | last7=Carswell | first7=A. | last8=Catling | first8=D. | last9=Clark | first9=B. |title= Introduction to special section on the phoenix mission: Landing site characterization experiments, mission overviews, and expected science |journal=J. Geophysical Research |volume= 113 |doi = 10.1029/2008JE003083 | bibcode=2008JGRE..11300A18S}}</ref><ref name='Dirt find'>{{cite web|url=http://www.space.com/scienceastronomy/090702-phoenix-soil.html |title=The Dirt on Mars Lander Soil Findings |publisher=SPACE.com |accessdate=December 19, 2010}}</ref>


[[Perchlorate]] (ClO<sub>4</sub>), a strong oxidizer, was confirmed to be in the soil. The chemical, when mixed with water, can lower the water freezing point in a manner similar to how salt is applied to roads to melt ice. It has been hypothesized that perchlorate may be allowing small amounts of liquid water to form on Mars today and may have formed visible gullies by eroding soil on steep slopes.<ref>{{cite journal | last1 = Hecht | first1 = MH| year = 2009 | last2 = Kounaves | first2 = SP | last3 = Quinn | first3 = RC | last4 = West | first4 = SJ | last5 = Young | first5 = SM | last6 = Ming | first6 = DW | last7 = Catling | first7 = DC | last8 = Clark | first8 = BC | last9 = Boynton | first9 = WV | title = Detection of Perchlorate and the Soluble Chemistry of Martian Soil at the Phoenix Lander Site | url = | journal=Science | volume = 325 | issue = 5936| pages = 64–67 | pmid = 19574385 | doi = 10.1126/science.1172466 |bibcode = 2009Sci...325...64H }}</ref><ref>{{cite news|authorlink= | title=Audio Recording of Phoenix Media Telecon for Aug. 5, 2008 | date=August 5, 2008 | publisher=NASA | url =http://www.jpl.nasa.gov/news/phoenix/podcast-phx20080805.php | work=Jet Propulsion Laboratory | accessdate =July 14, 2009 }}</ref>
[[Perchlorate]] (ClO<sub>4</sub>), a strong oxidizer, was confirmed to be in the soil. The chemical, when mixed with water, can lower the water freezing point in a manner similar to how salt is applied to roads to melt ice. It has been hypothesized that perchlorate may be allowing small amounts of liquid water to form on Mars today and may have formed visible gullies by eroding soil on steep slopes.<ref>{{cite journal | last1 = Hecht | first1 = MH| year = 2009 | last2 = Kounaves | first2 = SP | last3 = Quinn | first3 = RC | last4 = West | first4 = SJ | last5 = Young | first5 = SM | last6 = Ming | first6 = DW | last7 = Catling | first7 = DC | last8 = Clark | first8 = BC | last9 = Boynton | first9 = WV | title = Detection of Perchlorate and the Soluble Chemistry of Martian Soil at the Phoenix Lander Site | url = | journal=Science | volume = 325 | issue = 5936| pages = 64–67 | pmid = 19574385 | doi = 10.1126/science.1172466 |bibcode = 2009Sci...325...64H }}</ref><ref>{{cite news|authorlink= | title=Audio Recording of Phoenix Media Telecon for Aug. 5, 2008 | date=August 5, 2008 | publisher=NASA | url =http://www.jpl.nasa.gov/news/phoenix/podcast-phx20080805.php | work=Jet Propulsion Laboratory | accessdate =July 14, 2009 }}</ref>
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The orbiter helped scientists determine that much of the surface of Mars is covered by a thick smooth mantle that is thought to be a mixture of ice and dust.<ref name="Head, J. 2003">{{cite journal| last1= Head| first1= James W.| last2= Mustard| first2= John F.| last3= Kreslavsky| first3= Mikhail A.| last4= Milliken| first4= Ralph E.| last5= Marchant| first5= David R.| title= Recent ice ages on Mars |journal=Nature| volume= 426| issue= 6968 |pages= 797–802| year= 2003| pmid= 14685228 | doi = 10.1038/nature02114 |bibcode = 2003Natur.426..797H }}</ref><ref>Mellon, M. T., B. M. Jakosky, and S. E. Postawko (1997)[http://onlinelibrary.wiley.com/doi/10.1029/97JE01346/ The persistence of equatorial ground ice on Mars], J. Geophys. Res., 102(E8), 19357–19369, {{DOI|10.1029/97JE01346}}</ref><ref>John D. Arfstrom [http://www.lpi.usra.edu/meetings/climatology2012/pdf/8001.pdf A Conceptual Model of Equatorial Ice Sheets on Mars. J] Comparative Climatology of Terrestrial Planets (2012)</ref>
The orbiter helped scientists determine that much of the surface of Mars is covered by a thick smooth mantle that is thought to be a mixture of ice and dust.<ref name="Head, J. 2003">{{cite journal| last1= Head| first1= James W.| last2= Mustard| first2= John F.| last3= Kreslavsky| first3= Mikhail A.| last4= Milliken| first4= Ralph E.| last5= Marchant| first5= David R.| title= Recent ice ages on Mars |journal=Nature| volume= 426| issue= 6968 |pages= 797–802| year= 2003| pmid= 14685228 | doi = 10.1038/nature02114 |bibcode = 2003Natur.426..797H }}</ref><ref>Mellon, M. T., B. M. Jakosky, and S. E. Postawko (1997)[http://onlinelibrary.wiley.com/doi/10.1029/97JE01346/ The persistence of equatorial ground ice on Mars], J. Geophys. Res., 102(E8), 19357–19369, {{DOI|10.1029/97JE01346}}</ref><ref>John D. Arfstrom [http://www.lpi.usra.edu/meetings/climatology2012/pdf/8001.pdf A Conceptual Model of Equatorial Ice Sheets on Mars. J] Comparative Climatology of Terrestrial Planets (2012)</ref>


The ice mantle under the shallow subsurface is thought to result from frequent, major climate changes. Changes in Mars' orbit and tilt cause significant changes in the distribution of water ice from polar regions down to latitudes equivalent to Texas. During certain climate periods water vapor leaves polar ice and enters the atmosphere. The water returns to the ground at lower latitudes as deposits of frost or snow mixed generously with dust. The atmosphere of Mars contains a great deal of fine dust particles.<ref name="Head 2008 PNAS" /> Water vapor condenses on the particles, then they fall down to the ground due to the additional weight of the water coating. When ice at the top of the mantling layer goes back into the atmosphere, it leaves behind dust, which insulates the remaining ice.<ref name="IceAge&shy;">{{cite news| publisher=MLA NASA/Jet Propulsion Laboratory |date=December 18, 2003 |title=Mars may be emerging from an ice age |work=ScienceDaily |accessdate=February 19, 2009 |url=http://www.sciencedaily.com/releases/2003/12/031218075443.htm}}</ref>
The ice mantle under the shallow subsurface is thought to result from frequent, major climate changes. Changes in Mars' orbit and tilt cause significant changes in the distribution of water ice from polar regions down to latitudes equivalent to Texas. During certain climate periods water vapor leaves polar ice and enters the atmosphere. The water returns to the ground at lower latitudes as deposits of frost or snow mixed generously with dust. The atmosphere of Mars contains a great deal of fine dust particles.<ref name="Head 2008 PNAS" /> Water vapor condenses on the particles, then they fall down to the ground due to the additional weight of the water coating. When ice at the top of the mantling layer goes back into the atmosphere, it leaves behind dust, which insulates the remaining ice.<ref name="IceAge­">{{cite news| publisher=MLA NASA/Jet Propulsion Laboratory |date=December 18, 2003 |title=Mars may be emerging from an ice age |work=ScienceDaily |accessdate=February 19, 2009 |url=http://www.sciencedaily.com/releases/2003/12/031218075443.htm}}</ref>


In 2008, research with the Shallow Radar on the Mars Reconnaissance Orbiter provided strong evidence that the [[lobate debris aprons]] (LDA) in [[Hellas Planitia]] and in mid northern latitudes are [[glacier]]s that are covered with a thin layer of rocks. Its radar also detected a strong reflection from the top and base of LDAs, meaning that pure water ice made up the bulk of the formation.<ref name="Holt, J. 2008" /> The discovery of water ice in LDAs demonstrates that water is found at even lower latitudes.<ref name="Kieffer1992">{{cite book| author=Hugh H. Kieffer| title=Mars |url= http://books.google.com/books?id=NoDvAAAAMAAJ |accessdate=March 7, 2011 |year=1992|publisher=University of Arizona Press| isbn=978-0-8165-1257-7}}</ref>
In 2008, research with the Shallow Radar on the Mars Reconnaissance Orbiter provided strong evidence that the [[lobate debris aprons]] (LDA) in [[Hellas Planitia]] and in mid northern latitudes are [[glacier]]s that are covered with a thin layer of rocks. Its radar also detected a strong reflection from the top and base of LDAs, meaning that pure water ice made up the bulk of the formation.<ref name="Holt, J. 2008" /> The discovery of water ice in LDAs demonstrates that water is found at even lower latitudes.<ref name="Kieffer1992">{{cite book| author=Hugh H. Kieffer| title=Mars |url= http://books.google.com/books?id=NoDvAAAAMAAJ |accessdate=March 7, 2011 |year=1992|publisher=University of Arizona Press| isbn=978-0-8165-1257-7}}</ref>
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{{reflist|3}}
{{reflist|3}}


==Bibliography and recommended reading==
== Bibliography and recommended reading ==
*Boyce, Joseph, M. (2008). ''The Smithsonian Book of Mars;'' Konecky & Konecky: Old Saybrook, CT, ISBN 978-1-58834-074-0
*Boyce, Joseph, M. (2008). ''The Smithsonian Book of Mars;'' Konecky & Konecky: Old Saybrook, CT, ISBN 978-1-58834-074-0
*Carr, Michael, H. (1996). ''Water on Mars;'' Oxford University Press: New York, ISBN 0-19-509938-9.
*Carr, Michael, H. (1996). ''Water on Mars;'' Oxford University Press: New York, ISBN 0-19-509938-9.

Revision as of 04:28, 21 March 2014

An artist's impression of what ancient Mars may have looked like, based on geological data

Water on Mars exists today almost exclusively as ice, with a small amount present in the atmosphere as vapour.[1] The only place where water ice is visible at the surface is at the north polar ice cap.[2] However, abundant water ice is also present beneath the permanent carbon dioxide ice cap at the Martian south pole and in the shallow subsurface at more temperate latitudes.[3][4][5][6] More than five million cubic kilometers of ice have been identified at or near the surface of modern Mars, enough to cover the whole planet to a depth of 35 meters.[7] Even more ice is likely to be locked away in the deep subsurface.[8]

Some liquid water may occur transiently on the Martian surface today but only under certain conditions.[9][10] No large standing bodies of liquid water exist because the atmospheric pressure at the surface averages just 600 pascals (0.087 psi)—about 0.6% of Earth's mean sea level pressure—and because the global average temperature is far too low (210 K (−63 °C)), leading to either rapid evaporation or freezing. However, before about 3.8 billion years ago, Mars may have had a denser atmosphere and higher surface temperatures,[11][12] allowing vast amounts of liquid water on the surface,[13][14] possibly including a large ocean[15][16][17][18] that may have covered one-third of the planet.[19][20][21] Water has also apparently flowed across the surface for short periods at various intervals more recently in Mars' history.[22][23][24] On December 9, 2013, NASA reported that, based on evidence from the Curiosity rover studying Aeolis Palus, Gale Crater contained an ancient freshwater lake which could have been a hospitable environment for microbial life.[25][26]

Many lines of evidence indicate that water is abundant on Mars and has played a significant role in the planet's geologic history.[27][28] The present-day inventory of water on Mars can be estimated from spacecraft imagery, remote sensing techniques (spectroscopic measurements,[29][30] radar,[31] etc.,), and surface investigations from landers and rovers.[32][33] Geologic evidence of past water includes enormous outflow channels carved by floods; ancient river valley networks,[34][35] deltas, and lakebeds;[36][37][38][39] and the detection of rocks and minerals on the surface that could only have formed in liquid water.[40] Numerous geomorphic features suggest the presence of ground ice (permafrost)[41] and the movement of ice in glaciers, both in the recent past[42][43][44][45][46][47] and present.[48] Gullies and slope lineae along cliffs and crater walls suggest that flowing water continues to shape the surface of Mars, although to a far lesser degree than in the ancient past.

Although the surface of Mars was periodically wet and could have been hospitable to microbial life billions of years ago,[49] the current environment at the surface is dry and subfreezing, probably presenting an insurmountable obstacle for living organisms. In addition, Mars lacks a thick atmosphere, ozone layer, and magnetic field, allowing solar and cosmic radiation to strike the surface unimpeded. The damaging effects of ionizing radiation on cellular structure is another one of the prime limiting factors on the survival of life on the surface.[50][51] Therefore, the best potential locations for discovering life on Mars may be in subsurface environments.[52][53][54]

Dry channels near Warrego Valles

Understanding water on Mars is vital to assess the planet’s potential for harboring life and for providing usable resources for future human exploration. For this reason, “Follow the Water” was the science theme of NASA’s Mars Exploration Program (MEP) in the first decade of the 21st century. Discoveries by the 2001 Mars Odyssey, Mars Exploration Rovers (MERs), Mars Reconnaissance Orbiter (MRO), and Mars Phoenix Lander have been instrumental in answering key questions about water’s abundance and distribution on Mars. The ESA’s Mars Express orbiter has also provided essential data in this quest.[55] The Mars Odyssey, Mars Express, MER Opportunity rover, MRO, and Mars Science Lander Curiosity rover are still sending back data from Mars, and discoveries continue to be made.

On January 24, 2014, NASA reported that current studies on the planet Mars by the Curiosity and Opportunity rovers will now be searching for evidence of ancient life, including a biosphere based on autotrophic, chemotrophic and/or chemolithoautotrophic microorganisms, as well as ancient water, including fluvio-lacustrine environments (plains related to ancient rivers or lakes) that may have been habitable.[56][57][58][59] The search for evidence of habitability, taphonomy (related to fossils), and organic carbon on the planet Mars is now a primary NASA objective.[56]

Historical background

The notion of water on Mars preceded the space age by hundreds of years. Early telescopic observers correctly assumed that the white polar caps and clouds were indications of water's presence. For many years, the dark regions visible on the surface were interpreted as oceans.[60] These observations, coupled with the fact that Mars has a 24-hour day, led astronomer William Herschel to declare in 1784 that Mars probably offered its inhabitants "a situation in many respects similar to ours."[61]

By the start of the 20th century, most astronomers recognized that Mars was far colder and drier than Earth. The presence of oceans was no longer accepted, so the paradigm changed to an image of Mars as a "dying" planet with only a meager amount of water. The dark areas, which could be seen to change seasonally, were now thought to be tracts of vegetation.[62] The man most responsible for popularizing this view of Mars was Percival Lowell (1855–1916), who imagined a race of Martians constructing a network of canals to bring water from the poles to the inhabitants at the equator. Although generating tremendous public enthusiasm, Lowell's ideas were rejected by most astronomers. The consensus of the scientific establishment at the time is probably best summarized by English astronomer Edward Walter Maunder (1851–1928) who compared the climate of Mars to conditions atop a twenty-thousand-foot peak on an arctic island[63] where only lichen might be expected to survive.

In the meantime, many astronomers were refining the tool of planetary spectroscopy in hope of determining the composition of the Martian atmosphere. Between 1925 and 1943, Walter Adams and Theodore Dunham at the Mount Wilson Observatory tried to identify oxygen and water vapor in the Martian atmosphere, with generally negative results. The only component of the Martian atmosphere known for certain was carbon dioxide (CO2) identified spectroscopically by Gerard Kuiper in 1947.[64] Water vapor was not unequivocally detected on Mars until 1963.[65]

Mariner 4 acquired this image showing a barren planet (1965)

The composition of the polar caps, assumed to be water ice since the time of Cassini (1666), was questioned by a few scientists in the late 1800s who favored CO2 ice because of the planet's overall low temperature and apparent lack of appreciable water. This hypothesis was confirmed theoretically by Robert Leighton and Bruce Murray in 1966.[66] Today we know that the winter caps at both poles are primarily composed of CO2 ice, but that a permanent (or perennial) cap of water ice remains during the summer at the northern pole. At the southern pole, a small cap of CO2 ice remains during summer, but this cap too is underlain by water ice.

The final piece of the Martian climate puzzle was provided by Mariner 4 in 1965. Grainy television pictures from the spacecraft showed a surface dominated by impact craters, which implied that the surface was very old and had not experienced the level of erosion and tectonic activity seen on Earth. Little erosion meant that liquid water had probably not played a large role in the planet's geomorphology for billions of years.[67] Furthermore, the variations in the radio signal from the spacecraft as it passed behind the planet allowed scientists to calculate the density of the atmosphere. The results showed an atmospheric pressure less than 1% of Earth’s at sea level, effectively precluding the existence of liquid water, which would rapidly boil or freeze at such low pressures.[68] Thus, a vision of Mars was born of a world much like the Moon but with just a wisp of an atmosphere to blow the dust around. This view of Mars would last nearly another decade until Mariner 9 showed a much more dynamic Mars with hints that the planet’s past environment was more clement than the present one.

Water in weathering products (aqueous minerals)

The primary rock type on the surface of Mars is basalt, a fine-grained igneous rock made up mostly of the mafic silicate minerals olivine, pyroxene, and plagioclase feldspar.[69] When exposed to water and atmospheric gases, these minerals chemically weather into new (secondary) minerals, some of which may incorporate water into their crystalline structures, either as H2O or as hydroxyl (OH). Examples of hydrated (or hydoxylated) minerals include the iron hydroxide goethite (a common component of terrestrial soils); the evaporate minerals gypsum and kieserite; opalline silica; and phyllosilicates (also called clay minerals), such as kaolinite and montmorillonite. All of these minerals have been detected on Mars.[70]

File:CRISM Stokes PIA13214.jpg
Minerals identified in Stokes crater from CRISM and OMEGA spectrometers. Green = olivine; Light blue = montmorillonite; Red = iron-magnesium phyllosilicate; Dark blue = kaolinite; Orange = pyroxene.

One direct effect of chemical weathering is to consume water and other reactive chemical species, taking them from mobile reservoirs like the atmosphere and hydrosphere and sequestering them in rocks and minerals.[71] The amount of water in the Martian crust stored in hydrated minerals is currently unknown, but may be quite large.[72] For example, mineralogical models of the rock outcroppings examined by instruments on the Opportunity rover at Meridiani Planum suggest that the sulfate deposits there could contain up to 22% water by weight.[73]

On Earth, all chemical weathering reactions involve water to some degree.[74] Thus, many secondary minerals do not actually incorporate water but still require water to form. Some examples of anhydrous secondary minerals include many carbonates, some sulfates (e.g., anhydrite), and metallic oxides such as the iron oxide mineral hematite. On Mars, a few of these weathering products may theoretically form without water or with scant amounts present as ice or in thin molecular-scale films (monolayers).[75][76] However, the extent to which such exotic weathering processes operate on Mars is still uncertain. Minerals that incorporate water or form in the presence of water are generally termed “aqueous minerals.”

Aqueous minerals are sensitive indicators of the type of environment that existed when the minerals formed. The ease at which aqueous reactions occur (see Gibbs free energy) depend on the pressure, temperature, and on the concentrations of the gaseous and soluble species involved.[77] Two important properties are pH and oxidation-reduction potential (Eh). For example, the sulfate mineral jarosite forms only in low pH (highly acidic) water. Phyllosilicates usually form in water of neutral to high pH (alkaline). Eh is a measure is the oxidation state of an aqueous system. Together Eh and pH indicate the types of minerals that are thermodynamically most likely to form from a given set of aqueous components. Thus, past environmental conditions on Mars, including those conducive to life, can be inferred from the types of minerals present in the rocks.

Hydrothermal alteration

Aqueous minerals can also form in the subsurface by hydrothermal fluids migrating through pores and fissures. The heat source driving a hydrothermal system may be nearby magma bodies or residual heat from large impacts.[78] One important type of hydrothermal alteration in the Earth’s oceanic crust is serpentinization, which occurs when seawater migrates through ultramafic and basaltic rocks. The water-rock reactions result in the oxidation of ferrous iron in olivine and pyroxene to produce ferric iron (as the mineral magnetite) yielding molecular hydrogen (H2) as a byproduct. The process creates a highly alkaline and reducing (low Eh) environment favoring the formation of certain phyllosilicates (serpentine minerals) and various carbonate minerals, which together form a rock called serpentinite.[79] The hydrogen gas produced can be an important energy source for chemosynthtetic organisms or it can react with CO2 to produce methane gas, a process that has been considered as a non-biological source for the trace amounts of methane reported in the Martian atmosphere.[80] Serpentine minerals can also store a lot of water (as hydroxyl) in their crystal structure. A recent study has argued that hypothetical serpentinites in the ancient highland crust of Mars could hold as much as a 500-meter-thick global equivalent layer (GEL) of water.[81] Although some serpentine minerals have been detected on Mars, no widespread outcroppings are evident from remote sensing data.[82] However, this fact does not preclude the presence of large amounts of sepentinite hidden at depth in the Martian crust.

Weathering rates

The rates at which primary minerals convert to secondary aqueous minerals vary. Primary silicate minerals crystallize from magma under pressures and temperatures vastly higher than conditions at the surface of a planet. When exposed to a surface environment these minerals are out of equilibrium and will tend to interact with available chemical components to form more stable mineral phases. In general, the silicate minerals that crystallize at the highest temperatures (solidify first in a cooling magma) weather the most rapidly.[83] On the Earth and Mars, the most common mineral to meet this criterion is olivine, which readily weathers to clay minerals in the presence of water.

Despite this, the mineral olivine is widespread on Mars,[84] indicating that Mars' surface has not been pervasively altered by water. Nevertheless, abundant geological evidence suggests otherwise.[85][86][87][88][89]

Evidence from rocks and minerals

Today, it is widely accepted that Mars had abundant water very early in its history,[90][91] but all large areas of liquid water have since disappeared. A fraction of this water is however retained on modern Mars as both ice and locked into the structure of abundant water-rich materials, including clay minerals (phyllosilicates) and sulfates.[92][93][94][95][96] Studies of hydrogen isotopic ratios indicate that asteroids and comets from beyond 2.5 astronomical units (AU) provide the source of Mars' water,[97] which currently totals 6% to 27% of the Earth's present ocean.[97]

History of water on Mars numbers represent how many billion years ago

Martian meteorites

Mars meteorite ALH84001

Over 60 meteorites have been found that came from Mars.[98] Some of them contain evidence that they were exposed to water when on Mars. Some Martian meteorites called basaltic shergottites, appear (from the presence of hydrated carbonates and sulfates) to have been exposed to liquid water prior to ejection into space.[99][100] It has been shown that another class of meteorites, the nakhlites, were suffused with liquid water around 620 million years ago and that they were ejected from Mars around 10.75 million years ago by an asteroid impact. They fell to Earth within the last 10,000 years.[101]

In 1996, a group of scientists reported the possible presence of microfossils in the Allan Hills 84001, a meteorite from Mars.[102] Many studies disputed the validity of the fossils.[103][104] It was found that most of the organic matter in the meteorite was of terrestrial origin.[105]

Geomorphic evidence

Lakes and river valleys

The 1971 Mariner 9 spacecraft caused a revolution in our ideas about water on Mars. Huge river valleys were found in many areas. Images showed that floods of water broke through dams, carved deep valleys, eroded grooves into bedrock, and traveled thousands of kilometers. Areas of branched streams, in the southern hemisphere, suggested that rain once fell.[106][107][108] The numbers of recognised valleys has increased through time. Research published in June 2010 mapped 40,000 river valleys on Mars, roughly quadrupling the number of river valleys that had previously been identified.[21] Martian water-worn features can be classified into two distinct classes: 1) dendritic (branched), terrestrial-scale, widely distributed, Noachian-age valley networks and 2) exceptionally large, long, single-thread, isolated, Hesperian-age outflow channels. Recent work suggests that there may also be a class of currently enigmatic, smaller, younger (Hesperian to Amazonian) channels in the midlatitudes, perhaps associated with the occasional local melting of ice deposits.[109][110]

Kasei Valles—a major outflow channel—seen in MOLA elevation data. Flow was from bottom left to right. Image is approx. 1600 km across. The channel system extends another 1200 km south of this image to Echus Chasma.

Some parts of Mars show inverted relief. This occurs when sediments are deposited on the floor of a stream and then become resistant to erosion, perhaps by cementation. Later the area may be buried. Eventually, erosion removes the covering layer and the former streams become visible since they are resistant to erosion. Mars Global Surveyor found several examples of this process.[111][112] Many inverted streams have been discovered in various regions of Mars, especially in the Medusae Fossae Formation,[113] Miyamoto Crater,[114] Saheki Crater,[115] and the Juventae Plateau.[116][117]

Inverted stream channels in Antoniadi Crater. Location is Syrtis Major quadrangle

A variety of lake basins have been discovered on Mars.[118] Some are comparable in size to the largest lakes on Earth, such as the Caspian Sea, Black Sea, and Lake Baikal. Lakes that were fed by valley networks are found in the southern highlands. There are places that are closed depressions with river valleys leading into them. These areas are thought to have once contained lakes; one is in Terra Sirenum which had its overflow move through Ma'adim Vallis into Gusev Crater, explored by the Mars Exploration Rover Spirit. Another is near Parana Valles and Loire Vallis.[119] Some lakes are thought to have formed by precipitation, while others were formed from groundwater.[36][37] Lakes are estimated to have existed in the Argyre basin,[27][28] the Hellas basin,[38][120] and maybe in Valles Marineris.[39][120][121][122] It is likely that at times in the Noachian, very many craters hosted lakes. These lakes are consistent with a cold, dry (by Earth standards) hydrological environment somewhat like that of the Great Basin of the western USA during the Last Glacial Maximum.[123]

Research from 2010 suggests that Mars also had lakes along parts of the equator. Although earlier research had showed that Mars had a warm and wet early history that has long since dried up, these lakes existed in the Hesperian Epoch, a much later period. Using detailed images from NASA's Mars Reconnaissance Orbiter, the researchers speculate that there may have been increased volcanic activity, meteorite impacts or shifts in Mars' orbit during this period to warm Mars' atmosphere enough to melt the abundant ice present in the ground. Volcanoes would have released gases that thickened the atmosphere for a temporary period, trapping more sunlight and making it warm enough for liquid water to exist. In this study, channels were discovered that connected lake basins near Ares Vallis. When one lake filled up, its waters overflowed the banks and carved the channels to a lower area where another lake would form.[124][125] These dry lakes would be targets to look for evidence (biosignatures) of past life.

On September 27, 2012, NASA scientists announced that the Curiosity rover found direct evidence for an ancient streambed in Gale Crater, suggesting an ancient "vigorous flow" of water on Mars.[126][127][128][129] In particular, analysis of the now dry streambed indicated that the water ran at3.3 km/h (0.92 m/s),[126]{ possibly at hip-depth. Proof of running water came in the form of rounded pebbles and gravel fragments that could have only been weathered by strong liquid currents. Their shape and orientation suggests long-distance transport from above the rim of the crater, where a channel named Peace Vallis feeds into the alluvial fan.

Lake deltas

Delta in Eberswalde crater

Researchers have found a number of examples of deltas that formed in Martian lakes.[20] Finding deltas is a major sign that Mars once had a lot of liquid water. Deltas usually require deep water over a long period of time to form. Also, the water level needs to be stable to keep sediment from washing away. Deltas have been found over a wide geographical range,[36] though there is some indication that deltas may be concentrated around the edges of the putative former northern ocean of Mars.[130]

Groundwater

Layers may be formed by groundwater rising up gradually

By 1979 it was thought that outflow channels formed in single, catastrophic ruptures of subsurface water reservoirs, possibly sealed by ice, discharging colossal quantities of water across an otherwise arid Mars surface.[131][132] In addition, evidence in favor of heavy or even catastrophic flooding is found in the giant ripples in the Athabasca Vallis.[133][134] Many outflow channels begin at Chaos or Chasma features, providing evidence for the rupture that could have breached a subsurface ice seal.[120]

The branching valley networks of Mars are not however consistent with formation by sudden catastrophic release of groundwater, both in terms of their dendritic shapes which do not come from a single outflow point, and in terms of the discharges which apparently flowed along them.[135] Instead, some authors have argued that they were formed by slow seepage of groundwater from the subsurface essentially as springs.[136] In support of this interpretation, the upstream ends of many valleys in such networks begin with box canyon or "amphitheater" heads, which on Earth are typically associated with groundwater seepage. There is also little evidence of finer scale channels or valleys at the tips of the channels, which some authors have interpreted as showing the flow appeared suddenly from the subsurface with appreciable discharge, rather than accumulating gradually across the surface.[120] However, others have disputed the strong link between amphitheater heads of valleys and formation by groundwater for terrestrial examples,[137] and have argued that the lack of fine scale heads to valley networks is due to their removal by weathering or impact gardening.[120] Most authors however accept that most valley networks are at least partly influenced and shaped by groundwater seep processes.

The preservation and cementation of aeolian dune stratigraphy in Burns Cliff in Endurance Crater are thought to have been controlled by flow of shallow groundwater.[138]

Groundwater also plays a vital role in controlling broad scale sedimentation patterns and processes on Mars[139] According to this hypothesis, groundwater with dissolved minerals came to the surface, in and around craters, and helped to form layers by adding minerals —especially sulfate— and cementing sediments.[140][141][142][143][144][145] In other words, some layers may be formed by groundwater rising up depositing minerals and cementing existing, loose, aeolian sediments. The hardened layers are consequently more protected from erosion. This process may occur instead of layers forming under lakes. A study published in 2011 using data from the Mars Reconnaissance Orbiter, show that the same kinds of sediments exist in a large area that includes Arabia Terra.[146] It has been argued that areas which we know from satellite remote sensing are rich in sedimentary rocks are also those areas which are most likely to experience groundwater upwelling on a regional scale.[147]

Mars Ocean Hypothesis

The Mars Ocean Hypothesis proposes that the Vastitas Borealis basin was the site of an ocean of liquid water at least once,[13] and presents evidence that nearly a third of the surface of Mars was covered by a liquid ocean early in the planet's geologic history.[118][148] This ocean, dubbed Oceanus Borealis,[13] would have filled the Vastitas Borealis basin in the northern hemisphere, a region which lies 4–5 km (2.5–3 miles) below the mean planetary elevation. Two major putative shorelines have been suggested: a higher one, dating to a time period of approximately 3.8 billion years ago and concurrent with the formation of the valley networks in the Highlands, and a lower one, perhaps correlated with the younger outflow channels. The higher one, the 'Arabia shoreline', can be traced all around Mars except through the Tharsis volcanic region. The lower, the 'Deuteronilus', follows the Vastitas Borealis formation.[120]

A study in June 2010 concluded that the more ancient ocean would have covered 36% of Mars.[20][21] Data from the Mars Orbiter Laser Altimeter (MOLA), which measures the altitude of all terrain on Mars, was used in 1999 to determine that the watershed for such an ocean would have covered about 75% of the planet.[149] Early Mars would have required a warmer climate and denser atmosphere to allow liquid water to exist at the surface.[150][151] In addition, the large number of valley networks strongly supports the possibility of a hydrological cycle on the planet in the past.[140][152]

However, the existence of a primordial Martian ocean remains controversial among scientists, and the interpretations of some features as 'ancient shorelines' has been challenged.[153][154] One problem with the conjectured 2 billion years old (2 Ga) shoreline is that it is not flat — i.e. does not follow a line of constant gravitational potential. This could be due to a change in distribution in Mars' mass, perhaps due to volcanic eruption or meteor impact;[155] the Elysium volcanic province or the massive Utopia basin that is buried beneath the northern plains have been put forward as the most likely causes.[140]

Present water ice

Proportion of water ice present in the upper meter of the Martian surface for lower (top) and higher (bottom) latitudes. The percentages are derived through stoichiometric calculations based on epithermal neutron fluxes. These fluxes were detected by the Neutron Spectrometer aboard the 2001 Mars Odyssey spacecraft.

A significant amount of surface hydrogen has been observed globally by the Mars Odyssey Neutron Spectrometer and Gamma Ray Spectrometer.[156] This hydrogen is thought to be incorporated into the molecular structure of ice, and through stoichiometric calculations the observed fluxes have been converted into concentrations of water ice in the upper meter of the Martian surface. This process has revealed that ice is both widespread and abundant on the modern surface. Below 60 degrees of latitude, ice is concentrated in several regional patches, particularly around the Elysium volcanoes, Terra Sabaea, and northwest of Terra Sirenum, and exists in concentrations up to 18% ice in the subsurface. However, above 60 degrees latitude, ice is highly abundant. Polewards on 70 degrees of latitude, ice concentrations exceed 25% almost everywhere, and approach 100% at the poles.[157] More recently, the SHARAD and MARSIS radar sounding instruments have begun to be able to confirm whether individual surface features are ice rich. Due to the known instability of ice at current Martian surface conditions, it is thought that almost all of this ice must be covered by a veneer of rocky or dusty material.

The Mars Odyssey neutron spectrometer observations indicate that if all the ice in the top meter of the Martian surface were spread evenly, it would give a Water Equivalent Global layer (WEG) of at least ~14 cm—in other words, the globally averaged Martian surface is approximately 14% water.[158] The water ice currently locked in both Martian poles corresponds to a WEG of 30 m, and geomorphic evidence favors significantly larger quantities of surface water over geologic history, with WEG as deep as 500 m.[158] It is believed that part of this past water has been lost to the deep subsurface, and part to space, although the detailed mass balance of these processes remains poorly understood.[120] The current atmospheric reservoir of water is important as a conduit allowing gradual migration of ice from one part of the surface to another on both seasonal and longer timescales. However, it is insignificant in volume, with a WEG of no more than 10 µm.[158]

Ice patches

On July 28, 2005, the European Space Agency announced the existence of a crater partially filled with frozen water;[159] some then interpreted the discovery as an "ice lake".[160] Images of the crater, taken by the High Resolution Stereo Camera on board the European Space Agency's Mars Express orbiter, clearly show a broad sheet of ice in the bottom of an unnamed crater located on Vastitas Borealis, a broad plain that covers much of Mars' far northern latitudes, at approximately 70.5° North and 103° East. The crater is 35 km wide and about 2 km deep. The height difference between the crater floor and the surface of the water ice is about 200 metres. ESA scientists have attributed most of this height difference to sand dunes beneath the water ice, which are partially visible. While scientists do not refer to the patch as a "lake", the water ice patch is remarkable for its size and for being present throughout the year. Deposits of water ice and layers of frost have been found in many different locations on the planet.

As more and more of the surface of Mars has been imaged by the modern generation of orbiters, it has become gradually more apparent that there are probably many more patches of ice scattered across the Martian surface. Many of these putative patches of ice are concentrated in the Martian midlatitudes (~30-60 ° N/S of the equator). For example, many scientists believe that the widespread features in those latitude bands variously described as "latitude dependent mantle" or "pasted-on terrain" consist of dust- or debris-covered ice patches, which are slowly degrading.[120] A cover of debris is required both to explain the dull surfaces seen in the images that do not reflect like ice, and also to allow the patches to exist for an extended period of time without subliming away completely. These patches have been suggested as possible water sources for some of the enigmatic channelized flow features like gullies also seen in those latitudes.

Equatorial frozen sea

Surface features consistent with existing pack ice have been discovered in the southern Elysium Planitia.[118] What appear to be plates of broken ice, ranging in size from 30 m to 30 km, are found in channels leading to a flooded area of approximately the same depth and width as the North Sea. The plates show signs of break up and rotation that clearly distinguish them from lava plates elsewhere on the surface of Mars. The source for the flood is thought to be the nearby geological fault Cerberus Fossae which spewed water as well as lava aged some 2 to 10 million years. It was suggested that the water exited the Cerberus Fossae then pooled and froze in the low, level plains and that such lakes may still exist.[161] Not all scientists agree with these conclusions.[120][162][163]

Polar ice caps

The Mars Global Surveyor acquired this image of the Martian north polar ice cap in early northern summer.

Both the northern polar cap (Planum Boreum) and the southern polar cap (Planum Australe) are thought to grow in thickness during the winter and partially sublime during the summer. In 2004, the MARSIS radar sounder on the Mars Express satellite targeted the southern polar cap, and was able to confirm that ice there extends to a depth of 3.7 kilometres (2.3 mi) below the surface.[164] In the same year, the OMEGA instrument on the same orbiter revealed that the cap is divided into three distinct parts, with varying contents of frozen water depending on latitude. The first part is the bright part of the polar cap seen in images, centered on the pole, which is a mixture of 85% CO2 ice to 15% water ice.[4] The second part comprises steep slopes known as scarps, made almost entirely of water ice, that ring and fall away from the polar cap to the surrounding plains.[4] The third part encompasses the vast permafrost fields that stretch for tens of kilometres away from the scarps, and is not obviously part of the cap until the surface composition is analysed.[4][165] NASA scientists calculate that the volume of water ice in the south polar ice cap, if melted, would be sufficient to cover the entire planetary surface to a depth of 11 metres (36 ft).[164][166] Observations over both poles and more widely over the planet suggest melting all the surface ice would produce a water equivalent global layer 35 meters deep.[7]

Cross-section of a portion of the north polar ice cap of Mars, derived from satellite radar sounding.

On July 2008, NASA announced that the Phoenix lander had confirmed the presence of water ice at its landing site near the northern polar ice cap (at 68.2° latitude). This was the first ever direct observation of ice from the surface.[167] Two years later, the shallow radar on board the Mars Reconnaissance Orbiter took measurements of the north polar ice cap and determined that the total volume of water ice in the cap is 821,000 cubic kilometers (197,000 cubic miles). That is equal to 30% of the Earth's Greenland ice sheet, or enough to cover the surface of Mars to a depth of 5.6 meters.[168] Both polar caps reveal abundant fine internal layers when examined in HiRISE and Mars Global Surveyor imagery. Many researchers have attempted to use this layering to attempt to understand the structure, history, and flow properties of the caps,[120] although their interpretation is not straightforward.[169]

Lake Vostok in Antarctica may have implications for liquid water still existing on Mars because if water existed before the polar ice caps on Mars, it is possible that there is still liquid water below the ice caps.[170]

Ground ice

For many years, various scientists have suggested that some Martian surfaces look like periglacial regions on Earth.[171] By analogy with these terrestrial features, it has been argued for many years that these are regions of permafrost. This would suggest that frozen water lies right beneath the surface. A common feature in the higher latitudes, patterned ground, can occur in a number of shapes, including stripes and polygons. On the Earth, these shapes are caused by the freezing and thawing of soil.[172] There are other types of evidence for large amounts of frozen water under the surface of Mars, such as terrain softening, which rounds sharp topographical features.[173] Theoretical calculations and analysis have tended to bear out the possibility that these are features are formed by the effects of ground ice. Evidence from Mars Odyssey's Gamma Ray Spectrometer and direct measurements with the Phoenix lander have corroborated that many of these features are intimately associated with the presence of ground ice.[174]

Stages in scallop formation in Hellas quadrangle

Some areas of Mars are covered with cones that resemble those on Earth where lava has flowed on top of frozen ground. The heat of the lava melts the ice, then changes it into steam. The powerful force of the steam works its way through the lava and produces such rootless cones. These features can be found for example in Athabasca Valles, associated with lava flowing along this outflow channel. Larger cones may be made when the steam passes through thicker layers of lava.[175]

Scalloped topography

Certain regions of Mars display scalloped-shaped depressions. The depressions are suspected to be the remains of a degrading ice-rich mantle deposit. Scallops are caused by ice sublimating from frozen soil. This mantle material was probably deposited from the atmosphere as ice formed on dust when the climate was different due to changes in the tilt of the Mars pole (see "Ice ages", below).[176][177] The scallops are typically tens of meters deep and from a few hundred to a few thousand meters across. They can be almost circular or elongated. Some appear to have coalesced causing a large heavily pitted terrain to form. The process of forming the terrain may begin with sublimation from a crack. There are often polygonal cracks where scallops form, and the presence of scalloped topography seems to be an indication of frozen ground.[117][178]

These scalloped features are superficially similar to Swiss cheese features, found around the south polar cap. However, Swiss cheese features are thought to be due to cavities forming in a surface layer of solid carbon dioxide, rather than water ice—although the floors of these holes are probably H2O-rich.[179]

Glaciers

View of a 5-km-wide, glacial-like lobe deposit sloping up into a box canyon. The surface has 'moraines', deposits of rocks that show how the glacier advanced.

Many large areas of Mars either appear to host glaciers,or carry evidence that they used to be present. Much of the areas in high latitudes, especially the Ismenius Lacus quadrangle, are suspected to still contain enormous amounts of water ice.[180][181] Recent evidence has led many planetary scientists to believe that water ice still exists as glaciers across much of the Martian mid- and high latitudes, protected from sublimation by thin coverings of insulating rock and/or dust.[31][48] In January 2009, scientists released the results of a radar study of the glacier-like features called lobate debris aprons in an area called Deuteronilus Mensae, which found widespread evidence of ice lying beneath a few meters of rock debris.[48] Glaciers are associated with fretted terrain, and many volcanoes. Researchers have described glacial deposits on Hecates Tholus,[182] Arsia Mons,[183] Pavonis Mons,[184] and Olympus Mons.[185] Glaciers have also been reported in a number of larger Martian craters in the midlatitudes and above.

File:Reull Vallis lineated deposits.JPG
Reull Vallis with lineated floor deposits. Location is Hellas quadrangle

Glacier-like features on Mars are known variously as viscous flow features,[186] Martian flow features, lobate debris aprons,[48] or lineated valley fill,[43] depending on the form of the feature, its location, the landforms it is associated with, and the author describing it. Many, but not all, small glaciers seem to be associated with gullies on the walls of craters and mantling material.[187] The lineated deposits known as lineated valley fill are probably rock-covered glaciers which are found on the floors most channels within the fretted terrain found around Arabia Terra in the northern hemisphere. Their surfaces have ridged and grooved materials that deflect around obstacles. Lineated floor deposits may be related to lobate debris aprons, which have been proven to contain large amounts of ice by orbiting radar.[31][48] For many years, researchers interpreted that features called 'lobate debris aprons' were glacial flows and it was thought that ice existed under a layer of insulating rocks.[42][46][47] With new instrument readings, it has been confirmed that lobate debris aprons contain almost pure ice that is covered with a layer of rocks.[31][48]

A ridge interpreted as the terminal moraine of an alpine glacier. Location is Ismenius Lacus quadrangle

Moving ice carries rock material, then drops it as the ice disappears. This typically happens at the snout or edges of the glacier. On Earth, such features would be called moraines, but on Mars they are typically known as moraine-like ridges, concentric ridges, or arcuate ridges.[188] Because ice tends to sublime rather than melt on Mars, and because Mars's low temperatures tend to make glaciers "cold based" (frozen down to their beds, and unable to slide), the remains of these glaciers and the ridges they leave do not appear the exactly same as normal glaciers on Earth. In particular, Martian moraines tend to be deposited without being deflected by the underlying topography, which is thought to reflect the fact that the ice in Martian glaciers is normally frozen down and cannot slide.[120] Ridges of debris on the surface of the glaciers indicate the direction of ice movement. The surface of some glaciers has rough textures due to sublimation of buried ice. The ice evaporates without melting and leaves behind an empty space. Overlying material then collapses into the void.[189] Sometimes chunks of ice fall from the glacier and get buried in the land surface. When they melt, a more or less round hole remains. Many of these "kettle holes" have been identified on Mars.[190]

Despite strong evidence for glacial flow on Mars, there is little convincing evidence for landforms carved by glacial erosion, e.g., U-shaped valleys, crag and tail hills, arêtes, drumlins. Such features are abundant in glaciated regions on Earth, so their absence on Mars has proven puzzling. The lack of these landforms is thought to be related to the cold-based nature of the ice in most recent glaciers on Mars. Because the solar insolation reaching the planet, the temperature and density of the atmosphere, and the geothermal heat flux are all lower on Mars than they are on Earth, modelling suggests the temperature of the interface between a glacier and its bed stays below freezing and the ice is literally frozen down to the ground. This prevents it from sliding across the bed, which is thought to inhibit the ice's ability to erode the surface.[120]

Ice ages

North polar layered deposits of ice and dust

Mars has experienced large scale changes in the amount and distribution of ice on its surface in its relatively recent geological past, and as on Earth, these are known as ice ages. However, ice ages on Mars are very different from the ones that the Earth experiences. During a Martian ice age, the poles get warmer, and water ice then leaves the ice caps and is redeposited in mid latitudes.[191] The moisture from the ice caps travels to lower latitudes in the form of deposits of frost or snow mixed with dust. The atmosphere of Mars contains a great deal of fine dust particles, the water vapor condenses on these particles which then fall down to the ground due to the additional weight of the water coating. When ice at the top of the mantling layer returns to the atmosphere, it leaves behind dust which serves to insulate the remaining ice.[191] The total volume of water removed is a few percent of the ice caps, or enough to cover the entire surface of the planet under one meter of water. Much of this moisture from the ice caps results in a thick smooth mantle with a mixture of ice and dust.[176][192][193] This ice-rich mantle, a few meters thick, smoothes the land at lower latitudes, but in places it displays a bumpy texture. Multiple stages of glaciations probably occurred.[194] Because there are few craters on the current mantle, it is thought to be relatively young. It is thought that this mantle was laid in place during a relatively recent ice age.

Ice ages are driven by changes in Mars's orbit and tilt, which can be compared to terrestrial Milankovich cycles. However, orbital calculations show that Mars wobbles on its axis far more than Earth does. The Earth is stabilized by its proportionally large moon, so it only wobbles a few degrees. Mars, in contrast, may change its tilt—also known as its obliquity—by many tens of degrees.[177] When this obliquity is high, its poles get much more direct sunlight and heat; this causes the ice caps to warm and become smaller as ice sublimes. Adding to the variability of the climate, the eccentricity of the orbit of Mars changes twice as much as Earth's eccentricity. As the poles sublime, the ice is redeposited closer to the equator, which receive somewhat less solar insolation at these high obliquities. Computer simulations have shown that a 45° tilt of the Martian axis would result in ice accumulation in areas that display glacial landforms.[195] A 2008 study provided evidence for multiple glacial phases during Late Amazonian glaciation at the dichotomy boundary on Mars.[196]

Evidence for recent flows

Warm-season flows on slope in Newton Crater
Branched gullies
Group of deep gullies

Liquid water cannot exist in a stable form on the surface of Mars with its present low atmospheric pressure and low temperature, except at the lowest elevations for a few hours.[165][197] So, a geological mystery commenced when observations from NASA's Mars Reconnaissance Orbiter revealed gully deposits that were not there ten years ago, possibly caused by flowing salty water (brine) during the warmest months on Mars.[198][199][200][201][202][201][203][204][205][206] The images were of two craters called Terra Sirenum and Centauri Montes which appear to show the presence of liquid water flows on Mars at some point between 1999 and 2001.[201][207][208][209]

There is disagreement in the scientific community as to whether or not gullies are formed by liquid water. It is also possible that the flows that carve gullies are dry,[210] or perhaps lubricated by carbon dioxide.[211][212] Even if gullies are carved by flowing water at the surface, the exact source of the water and the mechanisms behind its motion are not well understood.[213]

In August 2011, NASA announced the discovery by Nepalese student Lujendra Ojha[214] of current seasonal changes on steep slopes below rocky outcrops near crater rims in the Southern hemisphere. Dark streaks were seen to grow downslope during the warmest part of the Martian Summer, then to gradually fade through the rest of the year, recurring cyclically between years.[10] The researchers suggested these marks were consistent with salty water (brines) flowing downslope and then evaporating, possibly leaving some sort of residue.[215] Because these flows have been the flows form and fade in sync with heat flux into the surface, many scientists feel these recurrent slope lineae are probably the best candidates for features formed by flowing water on Mars today.[199][216][217] The rate of growth of these features has been shown to be consistent with shallow groundwater flow downslope through a sandy substrate.[218]

Habitability assessment

Life is understood to require liquid water, but it is not the only essential requirement for life.[219][220][221] These requirements include water, an energy source, and materials necessary for cellular growth, while all under appropriate environmental conditions.[222] The confirmation that liquid water once flowed on Mars, the existence of nutrients, and the previous discovery of a past magnetic field that protected the planet from cosmic and solar radiation,[223][224] together strongly suggest that Mars could have had the environmental factors to support life.[49] To be clear, the find of past habitability is not evidence that Martian life has ever actually existed.

An electron microscope reveals bacteria-like structures in meteorite fragment ALH84001

When there is a magnetic field, the atmosphere is protected from erosion by solar wind, and ensures the maintenance of a dense atmosphere, necessary for liquid water to exist on the surface of Mars.[225][226] The two current ecological approaches for predicting the potential habitability of the Martian surface use 19 or 20 environmental factors, with emphasis on water availability, temperature, presence of nutrients, an energy source, and protection from solar ultraviolet and galactic cosmic radiation.[220][221] In particular, the damaging effect of ionising radiation on cellular structure is one of the prime limiting factors on the survival of life in potential astrobiological habitats.[50][51] Even at a depth of 2 meters beneath the surface, any microbes would likely be dormant, cryopreserved by the current freezing conditions, and so metabolically inactive and unable to repair cellular degradation as it occurs.[50][51][53][221][227][228][229]

Therefore, the best potential locations for discovering life on Mars may be at subsurface environments that have not been studied yet.[53][54][230][231][232] The extensive volcanism in the past, possibly created subsurface cracks and caves within different strata, and liquid water could have been stored in these subterraneous places, forming large aquifers with deposits of saline liquid water, minerals, organic molecules, and geothermal heat – potentially providing a current habitable environment away from the harsh surface conditions.[52][53][139][233][234][235][236]

Findings by probes

Mariner 9

Meander in Scamander Vallis, as seen by Mariner 9. Such images implied that large amounts of water once flowed on the surface of Mars.

The images acquired by the Mariner 9 Mars orbiter, launched in 1971, revealed the first direct evidence of past water in the form of dry river beds, canyons (including the Valles Marineris, a system of canyons over about 4,020 kilometres (2,500 mi) long), evidence of water erosion and deposition, weather fronts, fogs, and more.[237] The findings from the Mariner 9 missions underpinned the later Viking program. The enormous Valles Marineris canyon system is named after Mariner 9 in honor of its achievements.

Viking program

Streamlined islands in Maja Valles suggest that large floods occurred on Mars

By discovering many geological forms that are typically formed from large amounts of water, the two Viking orbiters and the two landers caused a revolution in our knowledge about water on Mars. Huge outflow channels were found in many areas. They showed that floods of water broke through dams, carved deep valleys, eroded grooves into bedrock, and traveled thousands of kilometers.[238] Large areas in the southern hemisphere contained branched valley networks, suggesting that rain once fell.[239] Many craters look as if the impactor fell into mud. When they were formed, ice in the soil may have melted, turned the ground into mud, then the mud flowed across the surface.[106][107][171][240] Regions, called "Chaotic Terrain," seemed to have quickly lost great volumes of water which caused large channels to form downstream. Estimates for some channel flows run to ten thousand times the flow of the Mississippi River.[241] Underground volcanism may have melted frozen ice; the water then flowed away and the ground collapsed to leave chaotic terrain. Also, general chemical analysis by the two Viking landers suggested the surface has been either exposed to or submerged in water in the past.[242][243]

Mars Global Surveyor

Map showing the distribution of hematite in Sinus Meridiani. This data was used to target the landing of the Opportunity rover that found definite evidence of past water.

The Mars Global Surveyor's Thermal Emission Spectrometer (TES) is an instrument able to determine the mineral composition on the surface of Mars. Mineral composition gives information on the presence or absence of water in ancient times. TES identified a large (30,000 km2) area in the Nili Fossae formation that contains the mineral olivine. It is thought that the ancient asteroid impact that created the Isidis basin resulted in faults that exposed the olivine. The discovery of olivine is strong evidence that parts of Mars have been extremely dry for a long time. Olivine was also discovered in many other small outcrops within 60 degrees north and south of the equator.[244] The probe has imaged several channels that suggest past sustained liquid flows, two of them are found in Nanedi Valles and in Nirgal Vallis.[202]

Inner channel (near top of the image) on floor of Nanedi Valles that suggests that water flowed for a fairly long period. Image from Lunae Palus quadrangle.

Mars Pathfinder

The Pathfinder lander recorded the variation of diurnal temperature cycle. It was coldest just before sunrise, about −78 °Celsius, and warmest just after Mars noon, about −8 °Celsius. These extremes occurred near the ground which both warmed up and cooled down fast. At this location, the highest temperature never reached the freezing point of water (0 °C), too cold for pure liquid water to exist on the surface.

Surface pressures varied diurnally over a 0.2 millibar range, but showed 2 daily minima and two daily maxima. The average daily pressure decreased from about 6.75 millibars to a low of just under 6.7 millbars, corresponding to when the maximum amount of carbon dioxide had condensed on the South Pole. The atmospheric pressure measured by the Pathfinder on Mars is very low —about 0.6% of Earth's, and it would not permit liquid water to exist on the surface.[245]

Other observations were consistent with water being present in the past. Some of the rocks at the Mars Pathfinder site leaned against each other in a manner geologists term imbricated. It is suspected that strong flood waters in the past pushed the rocks around until they faced away from the flow. Some pebbles were rounded, perhaps from being tumbled in a stream. Parts of the ground are crusty, maybe due to cementing by a fluid containing minerals.[246] There was evidence of clouds and maybe fog.[246]

Mars Odyssey

Complex drainage system in Semeykin Crater. Location is Ismenius Lacus quadrangle

The 2001 Mars Odyssey found much evidence for water on Mars in the form of images, and with its spectrometer, it proved that much of the ground is loaded with water ice. Mars has enough ice just beneath the surface to fill Lake Michigan twice.[5] In both hemispheres, from 55° latitude to the poles, Mars has a high density of ice just under the surface; one kilogram of soil contains about 500 g of water ice. But close to the equator, there is only 2% to 10% of water in the soil.[6] Scientists think that much of this water is also locked up in the chemical structure of minerals, such as clay and sulfates.[247][248] Although the upper surface contains a few percent of chemically-bound water, ice lies just a few meters deeper, as it has been shown in Arabia Terra, Amazonis quadrangle, and Elysium quadrangle that contain large amounts of water ice.[249] Analysis of the data suggests that the southern hemisphere may have a layered structure, suggestive of stratified deposits beneath a now extinct large water mass.[250]

Blocks in Aram showing a possible ancient source of water. Location is Oxia Palus quadrangle

The instruments aboard the Mars Odyssey are only able to study the top meter of soil, while the radar aboard the Mars Reconnaissance Orbiter can measure a few kilometers deep. In 2002, available data were used to calculate that if all soil surfaces were covered by an even layer of water, this would correspond to a global layer of water (GLW) 0.5 to 1.5 km deep.[251]

Thousands of images returned from Odyssey orbiter also support the idea that Mars once had great amounts of water flowing across its surface. Some images show patterns of branching valleys; others show layers that may have been formed under lakes; even river and lake deltas have been identified.[36][252] For many years researchers thought that glaciers existed under a layer of insulating rocks.[31][42][46][47][48] Lineated valley fill is one example of these rock-covered glaciers. They are found on the floors of some channels. Their surfaces have ridged and grooved materials that deflect around obstacles. Lineated floor deposits may be related to lobate debris aprons, which have been shown by orbiting radar to contain large amounts of ice.[31][48][48]

Phoenix

Permafrost polygons imaged by the Phoenix lander

The Phoenix lander also confirmed the existence of large amounts of water ice in the northern region of Mars.[253][254] This finding was predicted by previous orbital data and theory.[255] and was measured from orbit by the Mars Odyssey instruments.[6] On June 19, 2008, NASA announced that dice-sized clumps of bright material in the "Dodo-Goldilocks" trench, dug by the robotic arm, had vaporized over the course of four days, strongly implying that the bright clumps were composed of water ice which sublimes following exposure. Even though CO2 (dry ice) also sublimes under the conditions present, it would do so at a rate much faster than observed.[256] On July 31, 2008, NASA announced that Phoenix confirmed the presence of water ice at its landing site. During the initial heating cycle of a sample, the mass spectrometer detected water vapor when the sample temperature reached 0 °C.[167] Liquid water cannot exist on the surface of Mars with its present low atmospheric pressure and temperature, except at the lowest elevations for short periods.[165][197][253][257]

Perchlorate (ClO4), a strong oxidizer, was confirmed to be in the soil. The chemical, when mixed with water, can lower the water freezing point in a manner similar to how salt is applied to roads to melt ice. It has been hypothesized that perchlorate may be allowing small amounts of liquid water to form on Mars today and may have formed visible gullies by eroding soil on steep slopes.[258][259]

View underneath Phoenix lander showing water ice exposed by the landing retrorockets

Additionally, during 2008 and early 2009, a debate emerged within NASA over the presence of 'blobs' which appeared on photos of the vehicle's landing struts, which have been variously described as being either water droplets or 'clumps of frost'.[260][261][262][263]

For about as far as the camera can see, the landing site is flat, but shaped into polygons between 2 and 3 meters in diameter and are bounded by troughs that are 20 cm to 50 cm deep. These shapes are due to ice in the soil expanding and contracting due to major temperature changes. The microscope showed that the soil on top of the polygons is composed of rounded particles and flat particles, probably a type of clay.[264] Ice is present a few inches below the surface in the middle of the polygons, and along its edges, the ice is at least 8 inches deep. When the ice is exposed to the Martian atmosphere it slowly sublimes.[257]

Snow was observed to fall from cirrus clouds. The clouds formed at a level in the atmosphere that was around −65 °C, so the clouds would have to be composed of water-ice, rather than carbon dioxide-ice (CO2 or dry ice) because the temperature for forming carbon dioxide ice is much lower than −120 °C. As a result of mission observations, it is now suspected that water ice (snow) would have accumulated later in the year at this location.[265] The highest temperature measured during the mission, which took place during the Martian summer, was −19.6 °C, while the coldest was −97.7 °C. So, in this region the temperature remained far below the freezing point (0°C) of water.[266]

Mars Exploration Rovers

Close up of a rock outcrop
Thin rock layers, not all parallel to each other
Hematite spherules
Partly embedded spherules

The Mars Exploration Rovers, Spirit and Opportunity found a great deal of evidence for past water on Mars. The Spirit rover landed in what was thought to be a large lake bed. However, the lake bed had been covered over with lava flows, so evidence of past water was initially hard to detect. On March 5, 2004, NASA announced that Spirit had found hints of water history on Mars in a rock dubbed "Humphrey".[267]

As Spirit traveled in reverse in December 2007, pulling a seized wheel behind, the wheel scraped off the upper layer of soil, uncovering a patch of white ground rich in silica. Scientists think that it must have been produced in one of two ways.[268] One: hot spring deposits produced when water dissolved silica at one location and then carried it to another (i.e. a geyser). Two: acidic steam rising through cracks in rocks stripped them of their mineral components, leaving silica behind.[269] The Spirit rover also found evidence for water in the Columbia Hills of Gusev crater. In the Clovis group of rocks the Mossbauer spectrometer (MB) detected goethite,[270] that forms only in the presence of water.[271][272][273] iron in the oxidized form Fe+++,[274] carbonate-rich rocks, which means that regions of the planet once harbored water.[275][276]

The Opportunity rover was directed to a site that had displayed large amounts of hematite from orbit. Hematite often forms from water. The rover indeed found layered rocks and marble- or blueberry-like hematite concretions. Elsewhere on its traverse, Opportunity investigated aeolian dune stratigraphy in Burns Cliff in Endurance Crater. Its operators concluded that the preservation and cementation of these outcrops had been controlled by flow of shallow groundwater.[138] In its years of continuous operation, Opportunity is still sending back evidence that this area on Mars was soaked in liquid water in the past.[277][278]

However, the MER rovers had been finding evidence for ancient wet environments that were very acidic. In fact, what Opportunity has mostly discovered, or found evidence for, was sulphuric acid, a harsh chemical for life.[32][33][279][280] But in May 17, 2013, NASA announced that Opportunity found clay deposits that typically form in wet environments that are near neutral acidity. This find provides additional evidence about a wet ancient environment possibly favorable for life.[32][33]

Mars Reconnaissance Orbiter

Springs in Vernal Crater, as seen by HIRISE. These springs may be good places to look for evidence of past life because hot springs can preserve evidence of life forms for a long time. Location is Oxia Palus quadrangle.

The Mars Reconnaissance Orbiter's HiRISE instrument has taken many images that strongly suggest that Mars has had a rich history of water-related processes. A major discovery was finding evidence of ancient hot springs. If they have hosted microbial life, they may contain biosignatures.[281] Research published in January 2010, described strong evidence for sustained precipitation in the area around Valles Marineris.[116][117] The types of minerals there are associated with water. Also, the high density of small branching channels indicates a great deal of precipitation.

Rocks on Mars have been found to frequently occur as layers, called strata, in many different places.[282] Layers form by various ways, including volcanoes, wind, or water.[283] Light-toned rocks on Mars have been associated with hydrated minerals like sulfates and clay.[284]

Layers on the west slope of Asimov Crater. Location is Noachis quadrangle.

The orbiter helped scientists determine that much of the surface of Mars is covered by a thick smooth mantle that is thought to be a mixture of ice and dust.[176][285][286]

The ice mantle under the shallow subsurface is thought to result from frequent, major climate changes. Changes in Mars' orbit and tilt cause significant changes in the distribution of water ice from polar regions down to latitudes equivalent to Texas. During certain climate periods water vapor leaves polar ice and enters the atmosphere. The water returns to the ground at lower latitudes as deposits of frost or snow mixed generously with dust. The atmosphere of Mars contains a great deal of fine dust particles.[206] Water vapor condenses on the particles, then they fall down to the ground due to the additional weight of the water coating. When ice at the top of the mantling layer goes back into the atmosphere, it leaves behind dust, which insulates the remaining ice.[191]

In 2008, research with the Shallow Radar on the Mars Reconnaissance Orbiter provided strong evidence that the lobate debris aprons (LDA) in Hellas Planitia and in mid northern latitudes are glaciers that are covered with a thin layer of rocks. Its radar also detected a strong reflection from the top and base of LDAs, meaning that pure water ice made up the bulk of the formation.[31] The discovery of water ice in LDAs demonstrates that water is found at even lower latitudes.[171]

Research published in September 2009, demonstrated that some new craters on Mars show exposed, pure water ice.[287] After a time, the ice disappears, evaporating into the atmosphere. The ice is only a few feet deep. The ice was confirmed with the Compact Imaging Spectrometer (CRISM) on board the Mars Reconnaissance Orbiter.[288]

Curiosity rover

"Hottah" rock outcrop – an ancient streambed discovered by the Curiosity rover team (September 14, 2012) (close-up) (3-D version).
Rock outcrop on Mars – compared with a terrestrial fluvial conglomerate – suggesting water "vigorously" flowing in a stream.[126][127][128]

Very early in its ongoing mission, NASA's Curiosity rover discovered unambiguous fluvial sediments on Mars. The properties of the pebbles in these outcrops suggested former vigorous flow on a streambed, with flow between ankle- and waist-deep. These rocks were found at the foot of an alluvial fan system descending from the crater wall, which had previously been identified from orbit.[126][127][128]

On October 2012, the first X-ray diffraction analysis of a Martian soil was performed by Curiosity. The results revealed the presence of several minerals, including feldspar, pyroxenes and olivine, and suggested that the Martian soil in the sample was similar to the weathered basaltic soils of Hawaiian volcanoes. The sample used is composed of dust distributed from global dust storms and local fine sand. So far, the materials Curiosity has analyzed are consistent with the initial ideas of deposits in Gale Crater recording a transition through time from a wet to dry environment.[289]

On December 2012, NASA reported that Curiosity performed its first extensive soil analysis, revealing the presence of water molecules, sulfur and chlorine in the Martian soil.[290][291] And on March 2013, NASA reported evidence of mineral hydration, likely hydrated calcium sulfate, in several rock samples including the broken fragments of "Tintina" rock and "Sutton Inlier" rock as well as in veins and nodules in other rocks like "Knorr" rock and "Wernicke" rock.[292][293][294] Analysis using the rover's DAN instrument provided evidence of subsurface water, amounting to as much as 4% water content, down to a depth of 60 cm (2.0 ft), in the rover's traverse from the Bradbury Landing site to the Yellowknife Bay area in the Glenelg terrain.[292]

On September 26, 2013, NASA scientists reported the Mars Curiosity rover detected abundant chemically-bound water (1.5 to 3 weight percent) in soil samples at the Rocknest region of Aeolis Palus in Gale Crater.[295][296][297][298][299][300] In addition, NASA reported the rover found two principal soil types: a fine-grained mafic type and a locally derived, coarse-grained felsic type.[297][299][301] The mafic type, similar to other martian soils and martian dust, was associated with hydration of the amorphous phases of the soil.[301] Also, perchlorates, the presence of which may make detection of life-related organic molecules difficult, were found at the Curiosity rover landing site (and earlier at the more polar site of the Phoenix lander) suggesting a "global distribution of these salts".[300] NASA also reported that Jake M rock, a rock encountered by Curiosity on the way to Glenelg, was a mugearite and very similar to terrestrial mugearite rocks.[302]

On December 9, 2013, NASA reported that the planet Mars had a large freshwater lake (which could have been a hospitable environment for microbial life) based on evidence from the Curiosity rover studying the plain Aeolis Palus near Mount Sharp in Gale Crater.[25][26]

Images

River valleys and outflow channels
Gullies
Glaciers
Ground ice
Ancient lake

See also

References

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