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Revision as of 17:10, 7 June 2007
An ink is a liquid containing various pigments and/or dyes used for coloring a surface to render an image or text. Ink is used for drawing or writing with a pen or brush. Thicker inks, in paste form, are used extensively in letterpress and lithographic printing.
Types of ink
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Early varieties include Egyptian ink, various natural dyes made from metals, the husk or outer covering of beans or seeds, and sea creatures like the squid (known as sepia). India ink is black and originated in Asia. Walnut ink and iron gall ink are thought to have been used by many of the old masters for drawing. However, there is no proof of this. Walnut Inks, if they were used, would have faded fairly quickly.
Pigmented inks
Pigmented inks contain other agents that ensure adhesion of the pigment to the surface and prevent it from being removed by mechanical abrasion. These materials are typically referred to as resins (in solvent-based inks) or binding agents (in water-based inks).
Pigmented inks are advantageous when printing on paper because the pigment stays on the surface of the paper. This is desirable because more ink on the surface means that less ink needs to be used to create the same intensity of color.
Pigments are the main components of ink, containing the different colors. The size of the pigment is very important for the ability to diffuse in the solution inks. Qualities such as hue, saturation, and brightness are inherent in the ink, and vary dependent on the source and type of pigment.
Dyes in inks
Dye-based inks are generally much stronger than pigment-based inks and can produce much more color of a given density per unit of mass. However, because dyes are dissolved in the liquid phase, they have a tendency to soak into paper, thus making the ink less efficient and also potentially allowing the ink to bleed at the edges of an image, producing poor quality printing.
To circumvent this problem, dye-based inks are made with solvents that dry rapidly or are used with quick-drying methods of printing, such as blowing hot air on the fresh print. Other methods include harder paper sizing and more specialized paper coatings. The latter is particularly suited to inks used in non-industrial settings (which must conform to tighter toxicity and emission controls), such as inkjet printer inks. Another technique involves coating the paper with a charged coating. If the dye has the opposite charge, it is attracted to and retained by this coating, while the solvent soaks into the paper. Cellulose, the material that paper is made of, is naturally charged, and so a compound that complexes with both the dye and the paper's surface will aid retention at the surface. Such a compound in common use in ink-jet printing inks is polyvinyl pyrrolidone.
An additional advantage of dye-based ink systems is that the dye molecules interact chemically with other ink ingredients. This means that they can benefit more than pigmented ink from optical brighteners and color-enhancing agents designed to increase the intensity and appearance of dyes. Because dyes get their color from the interaction of electrons in their molecules, the way in which the electrons can move is determined by the charge and extent of electron delocalization in the other ink ingredients. The color emerges as a function of the light energy that falls on the dye. Thus, if an optical brightener or color enhancer absorbs light energy and emits it through or with the dye, the appearance changes, as the spectrum of light re-emitted to the observer changes.
A disadvantage of dye-based inks is that they can be more susceptible to fading, especially when exposed to ultraviolet radiation as in sunlight.
History of ink
Approximately 5000 years ago, an ink for blacking the raised surfaces of pictures and texts carved in stone was developed in China. This early ink was a mixture of soot from pine smoke, lamp oil, and gelatin from animal skins and musk. Other early cultures also developed many colors of ink from available berries, plants and minerals.
In an article for the Christian Science Monitor, Sharon J. Huntington describes these other historical inks:
About 1,600 years ago, a popular ink recipe was created. The recipe was used for centuries. Iron "salts," such as ferrous sulfate (made by treating iron with sulfuric acid), was mixed with tannin from gallnuts (they grow on trees) and a thickener. When first put to paper, this ink is bluish-black. Over time it fades to a dull brown.
Scribes in medieval Europe (about AD 800 to 1500) wrote on sheepskin parchment. One 12th century ink recipe called for hawthorn branches to be cut in the spring and left to dry. Then the bark was pounded from the branches and soaked in water for eight days. The water was boiled until it thickened and turned black. Wine was added during boiling. The ink was poured into special bags and hung in the sun. Once dried, the mixture was mixed with wine and iron salt over a fire to make the final ink.
In the 15th century, a new type of ink had to be developed in Europe for the printing press by Johannes Gutenberg. Two types of ink were prevalent at the time: the Greek and Roman writing ink (soot, glue, and water) and the 12th century variety composed of ferrous sulfate, gall, gum, and water.[1] Neither of these handwriting inks could adhere to printing surfaces without creating blurs. Eventually an oily, varnish-like ink made of soot, turpentine, and walnut oil was created specifically for the printing press.
Modern ink applications
Up until a few years ago, consumers had very little interest in ink other than refills for their pens. Fountain pens became a novelty as the disposable ball point pen took over the market. The introduction of home computing led to home printing. Today, in developed nations, it is rare to find a residence or a business that does not have a printing capability. As a result, buying ink in the form of a cartridge or having that cartridge refilled at an inkjet island in a local mall has once again become a part of the day-to-day shopping experience, similar to buying a bottle of ink fifty years ago.
Ink refilling services for printer cartridges are offered by large, official printing companies as well as smaller, "unofficial" refill companies. Customers can often cut printing costs by using refill services from a refill company, or buying the new non-OEM brands instead of refilling.
Poisonous ink
There is a misconception that ink isn't harmful even if swallowed, but this is false. Once ingested, ink can be very hazardous to one's health. Certain inks, such as those used in printers, and even those found in a common pen can be harmful. Though ink will not cause death, it can cause side effects such as a damaged nervous system and severe headaches. These effects are caused by a chemical known as p-Anisidine, used in the process of creating the ink's color and shine. The poison control center has stated that any consumption of ink should be reported to a local hospital or poison control center.
References
- "Think Ink!" by Sharon J. Huntington, Christian Science Monitor, September 21, 2004, retrieved January 17, 2006.
- "A History of Technology and Invention" by Maurice Audin, page 630.
- Ainsworth, Mitchell, C., "Inks and Their Composition and Manufacture," Charles Griffin and Company Ltd, 1904.
See also
External links
- Detailed online textbook on inks, antiquity-1904
- Extensive list of ink recipes
- Tips on removing ink stains from clothing
- Printing inks and related subjects - online lecture by University of Printing and Media, Stuttgart, Germany
- Ink chemistry - by prof.Joy Kunjappu
- ^ Many recipes for iron gall inks are featured in A booke of secrets: shewing diuers waies to make and prepare all sorts of inke... tr. out of Dutch into Englishe by W.P. [i.e. William Philip], London, 1596.