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Basic lead phosphite

Basic lead phosphite
Names
Other names
basic lead phosphonite
Identifiers
3D model (JSmol)
UN number 2989
  • InChI=1S/2HO3P.H2O.4O.6Pb/c2*1-4(2)3;;;;;;;;;;;/h2*1H;1H2;;;;;;;;;;/q2*-2;;;;;;;;;;2*+2
    Key: XTQIDVCLCLXOKX-UHFFFAOYSA-N
  • O.OP([O-])[O-].OP([O-])[O-].O=[Pb].O=[Pb].O=[Pb].O=[Pb].[Pb+2].[Pb+2]
Properties
H3O6PPb3
Molar mass 751.6 g·mol−1
Appearance white solid
Hazards
GHS labelling:
GHS02: FlammableGHS08: Health hazard
Danger
H228, H350, H360, H370, H372
P201, P202, P210, P240, P241, P260, P264, P270, P280, P281, P307+P311, P308+P313, P314, P321, P370+P378, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Basic lead phosphite is an inorganic compound with the proposed composition Pb3O(OH)2(HPO3).[1] The compound contains the phosphite anion, which provides the reducing properties associated with the application of this material.

It is widely used as a stabilizer for chlorine-containing polymers, especially polyvinylchloride.[2] Other lead phosphites are known, including normal lead phosphite, PbHPO3, although the basic salt is especially effective.[3]

References

  1. ^ Grossman, Richard F.; Krausnick, Dale (1998). "The structure of lead stabilizers. 2: Basic salts of inorganic acids". Vinyl and Additive Technology. 4 (3): 179–181. doi:10.1002/vnl.10038. S2CID 95532627.
  2. ^ Bettermann, Gerhard; Krause, Werner; Riess, Gerhard; Hofmann, Thomas (2000). "Phosphorus Compounds, Inorganic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a19_527. ISBN 978-3527306732..
  3. ^ Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2015). "Synthesis, crystal structures and properties of lead phosphite compounds". Journal of Solid State Chemistry. 231: 198–203. Bibcode:2015JSSCh.231..198S. doi:10.1016/j.jssc.2015.08.031.


Quelle: http://en.wikipedia.org/wiki/Basic_lead_phosphite